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Effect of extractant on arsenic(V) recovery from sulfuric acid solutions

  • Solvent Extraction, Liquid Membranes, and Micellar Separations
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Abstract

Extraction of arsenic(V) from sulfuric acid solutions with various extractants in multistage counter-current extraction-stripping systems was compared. The extraction ability of the extractants studied showed the following order: ENIM 100>TBP=CYANEX 923>2-methylhexanol. The extraction depends significantly on the number of extraction stages and the phase ratios in extraction. The effects of the number of stripping stages and the phase ratio in stripping are less important.

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References

  1. A. De Schepper, Extraction Metallurgy '85, IMM London 1985, p. 167.

  2. P. G. Hall, R. W. Armstrong, B. Middlin, D. A. Windborne, Townsville, Australia, presented at 114th TMS AIME Annual Meeting, Feb., 1985, New York, in: Energy Reduction Techniques in Metal Electrochemical Processes,R. G. Bautista, R. J. Wesley (Eds), Warrendale, Pa., 1985, p. 61.

  3. Y. Jiaoyong, L. Daxing, Z. Huifang, J. Kaixi, Solvent Extraction 1990, Part B,T. Sekine (Ed.), Elsevier, Amsterdam, 1992, p. 1205.

    Google Scholar 

  4. T. Totsuka, K. Sasaki, T. Nagai, Met. Rev. MMIJ, Symp. Proc. 3 (1986) 146.

    CAS  Google Scholar 

  5. R. Shibayama, T. Nagai, Solvent Extraction 1990, Part B,T. Sekine (Ed.), Elsevier, Amsterdam, 1992, p. 1193.

    Google Scholar 

  6. S. S. Naboychenko, I. V. Zauzolkov, V. M. Shabalin, Tsvet, Met., 1 (1990) 42 (in Russian).

    Google Scholar 

  7. A. De Schepper, A. Van Peteghem, US. Pat. 4,061,564 (1977); Ger. Pat. 2,615,638 (1976).

  8. J. Szymanowski, M. Wiśniewski, Polish J. Appl. Chem. (in press).

  9. W. A. Rickelton, in: Solvent Extraction in the Process Industries, Vol. 3,D. H. Logsdail, M. J. Slater (Eds), Elsevier, London, 1993, p. 731.

    Google Scholar 

  10. R. Marr, H. J. Bart, R. Wachter, US Pat. 4,503,015 (1985).

  11. D. B. Dreisinger, B. J. Y. Leong, B. J. Balint, M. H. Beyad, in: Solvent Extraction in the Process Industries,D. H. Logsdail, J. Slater (Eds), Elsevier, London, 1993, p. 1271.

    Google Scholar 

  12. W. Schwab, R. Kehl, US Pat. 4 834 951 (1989).

  13. A. Baradel, R. Guerriero, L. Meregalli, I. Vittadini, J. Met., 38 (1986) 32.

    CAS  Google Scholar 

  14. R. Guerriero, G. Veronese, A. Baradel, R. Rivola, US Pat. 4,547,346 (1985).

  15. A. Baradel, R. Guerriero, PCT Int. Appl. Wo 87 00, 867 (1987).

    Google Scholar 

  16. A. Baradel, R. Guerriero, L. Meregalli, I. Vittadini, ISEC'86, Vol.2. Preprints, 1986, p. 401.

  17. A. Baradel, R. Guerriero, G. Veronese, Eur. Pat. 180,110 (1988).

    Google Scholar 

  18. D. G. E. Kerfoof, US Pat 4, 115,512 (1978); UK Pat. 1,551,023 (1977).

  19. The recovery of mineral acids with CYANEX 923, Cyanamid Canada Inc., Technical Bulletin, No. 89-01.

  20. M. B. Bogacki, J. Szymanowski, Ind. Eng. Chem. Res., 29 (1990) 601.

    Article  CAS  Google Scholar 

  21. M. B. Bogacki, J. Szymanowski, Int. Eng. Chem. Res., 31 (1992) 328.

    CAS  Google Scholar 

  22. M. B. Bogacki, G. Cote, J. Szymanowski, D. Bauer, Ind. Eng. Chem. Res., 31 (1992) 1768.

    CAS  Google Scholar 

  23. M. B. Bogacki, G. Cote, J. Szymanowski, Sep. Sci. Technol., 28 (1993) 1783.

    CAS  Google Scholar 

  24. M. B. Bogacki, G. Cote, J. Szymanowski, Ind. Eng. Chem. Res., 32 (1993) 2775.

    Article  CAS  Google Scholar 

  25. M. B. Bogacki, K. Alejski, J. Szymanowski, Comp. Chem. Eng., 9 (1989) 1081.

    Google Scholar 

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Bogacki, M.B., Wiśniewski, M. & Szymanowski, J. Effect of extractant on arsenic(V) recovery from sulfuric acid solutions. J Radioanal Nucl Chem 228, 57–61 (1998). https://doi.org/10.1007/BF02387300

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  • DOI: https://doi.org/10.1007/BF02387300

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