Abstract
The sintering behaviour ofβ-Sialon composition powders with 5 mol% Y2O3-ZrO2 additives at 1750°C for 1.5 h in nitrogen or argon atmospheres was studied.β-Sialon composition powders could be pressureless-sintered to about 93% theoretical density by the addition of 5 wt% 5 mol% Y2O3-ZrO2. By HIPing the pressureless-sintered bodies the density was increased to higher than 98% theoretical density, and uniform submicrometre ZrO2 particles were homogeneously dispersed in theβ-Sialon matrix, resulting in an increase of fracture toughness,K 1c, from 5.1 to about 5.7 MN m−1.5. Increasing the amount of tetragonal ZrO2 transformable to monoclinic phase in theβ-Sialon matrix increasedK 1c.
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R. W. RICE and W. J. McDONOUGH,J. Amer. Ceram. Soc. 58 (1975) 264.
A. F. HAMPTON and H. C. GRAHAM,Oxid. Met. 10 (1976) 239.
A. W. J. M. RAE, D. P. THOMPSON and K. H. JACK, “Ceramics for High Performance Applications -11”, edited by J. J. Burke, E. N. Lemoe and R. N. Katz (Brook Hill, Chestnut Hill, Massachusetts, 1978) pp. 1039–67.
S. W. FREIMAN, J. J. MECHOLSKY, W. J. McDONOUGH and R. W. RICE, —ibid. “ pp. 1069–76.
S. DUTTA and B. BUZEK,J. Amer. Ceram. Soc. 67 (1984) 89.
N. Claussen and J. Jpahn,ibid. 61 (1984) c-94.
F. F. LANGE, —ibid.63 (1980) 38.
A. K. TJERNLUND, R. POMPE and R. CARLSSON, Extended Abstracts of the 3rd International Conference on the Science and Technology of Zirconia (1986) p. 222.
W. A. SANDERS and D. M. MIESKOWSKI,Adv. Ceram. Mater. 1 (1986) 166.
S. HIRANO, T. HAYASHI and T. NAKASHIMA,Adv. Ceram. 24 (1988) 1123.
K. NIIHARA, R. MORENA and D. P. H. HASSELMAN,J. Mater. Sci. Lett. 1 (1982) 13.
T. VASILOS, R. M. CANNON and B. J. WUENSCH, NASA-CR-159585 (1979).
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Hirano, SI., Hayashi, T. & Nakashima, T. Sintering ofβ-sialon with 5mol% Y2O3-ZrO2 additives. J Mater Sci 24, 3712–3716 (1989). https://doi.org/10.1007/BF02385761
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DOI: https://doi.org/10.1007/BF02385761