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Electron attachment processes in halomethanes

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Abstract

We have investigated thermal electron capture processes in the mixtures of halomethanes and carbon dioxide (in excess) using the electron swarm method. We have found that except the very slow second order reactions (single collision) there occur processes involving homo-(RX)2 or heterogeniouos (RX·CO2) van der Waals complexes (multi-body pressure dependent processes) which are at least a few times faster at atmospheric pressures. The mechanism and the kinetics of some of these processes are presented.

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References

  1. L. G. Christophorou, Atomic and Molecular Radiation Physics, Wiley Interscience, New York, 1971.

    Google Scholar 

  2. D. L. McCorkle, A. A. Christodoulides, L. G. Christophorou, Electron Molecule Interaction and their Applications, Vol. 1, Academic Press, New York, 1984.

    Google Scholar 

  3. D. A. Armstrong, Radiation Chemistry: Principles and Applications, VCH, Weinheim, Germany, 1987, p. 263.

    Google Scholar 

  4. G. R. A. Johnson, J. L. Redpath, J. Phys. Chem., 72 (1968) 765.

    CAS  Google Scholar 

  5. J. D. Chen, D. A. Armstrong, J. Chem. Phys., 48 (1968) 2310.

    CAS  Google Scholar 

  6. A. Stamatovic, P. Scheier, T. D. Märk, Z. Phys. D-Atoms, Molec. Clust., 6 (1987) 351.

    CAS  Google Scholar 

  7. M. Knapp, O. Echt, D. Kreisle, T. D. Märk, E. Recknagel, Physics and Chemistry of Small Clusters, Plenum Publishing Corp., London, 1987, p. 693.

    Google Scholar 

  8. H. Haberland, C. Ludewigt, H. G. Schindler, D. R. Worsnop, Phys. Rev. A., 36 (1987) 967.

    Article  CAS  Google Scholar 

  9. J. V. Coe, G. H. Lee, J. G. Eaton, S. T. Arnold, H. W. Sarkas, K. H. Bowen, C. Ludewigt, H. Haberland, D. R. Worsnop, J. Chem. Phys., 92 (1990) 3980.

    Article  CAS  Google Scholar 

  10. A. Kuhn, E. Illenberger, J. Phys. Chem., 93 (1989) 7060.

    Google Scholar 

  11. E. Illenberger, Chem. Rev., 92 (1992) 1589.

    Article  CAS  Google Scholar 

  12. I. Handorf, E. Illenberger, L. Lehr, J. Manz, Chem. Phys. Lett., 231 (1994) 460.

    Google Scholar 

  13. I. Szamrej, M. Forys, Radiat. Phys. Chem., 33 (1989) 393.

    CAS  Google Scholar 

  14. O. W. Dmitriev, W. Tchórzewska, I. Szamrej, M. Forys, Radiat. Phys. Chem., 40 (1992) 547.

    CAS  Google Scholar 

  15. J. Kopyra, A. Rosa, I. Szamrej, J. Radioanal. Nucl. Chem., (1998).

  16. I. Szamrej, W. Tchórzewska, H. Kość, M. Foryś, Radiat. Phys. Chem., 47 (1996) 269.

    Article  CAS  Google Scholar 

  17. I. Szamrej, H. Kość, M. Foryś, Radiat. Phys. Chem., 48 (1996) 69.

    CAS  Google Scholar 

  18. I. Szamrej, J. Jówko, M. Foryś, Radiat. Phys. Chem., 48 (1996) 65.

    CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Chemistry Department, Agricultural and Teachers University, Siedlce, Poland

    I. Szamrej

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  1. I. Szamrej
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Szamrej, I. Electron attachment processes in halomethanes. J Radioanal Nucl Chem 232, 63–66 (1998). https://doi.org/10.1007/BF02383713

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  • DOI: https://doi.org/10.1007/BF02383713

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