Abstract
Preliminary results on composite gel electrolytes (CGEs) with fumed silica (SiO2) as filler added to gel polymeric electrolyte (GPE) based on PMMA, LiCF3SO3 and PC are presented in this paper. Added fumed silica is seen to enhance the mechanical properties of the GPE without changing the σ significantly. The high ionic conductivity (×10−3 S/cm), high transmission in the visible region and nominal variance of σ and ν over a wide temperature window makes these CGEs potential electrolytes for electrochromic windows (ECWs).
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References
M.A. Depaoli, M.G. Casalbore and W.A. Gazotti, Electrochim. Acta44, 2983 (1991).
O. Bohnke, C. Rousselot, P.A. Gillet and C. Truche J. Electrochem. Soc.139, 1862 (1992).
J.Y. Song, Y.Y. Wang and C.C. Wan, J. Power Sources77, 183 (1999).
S.A. Agnihotry, Nidhi Pradeep and S.S. Sekhon, Solid State Ionics136–137, 573 (2000).
M. Deepa, M. Sharma, S.A. Agnihotry and R. Chandra, J. Mater. Sci.37, 1759 (2002).
M. Deepa, N. Sharma, S.A. Agnihotry, S. Singh, T. Lal and R. Chandra, Solid State Ionics152–153, 253 (2002).
K.H. Lee, Y.G. Lee, J.K. Park, and D.Y. Seung, Solid State Ionics133, 257 (2000).
J. Adebhar, N. Byrne, M. Forsyth, D.R. MacFarlane and P. Jacobsson, Electrochim. Acta48, 2099 (2003).
G.B. Appetecchi, P. Romagnoli and B. Scrosati, Electrochem. Commun.3, 281 (2001).
Technical Bulletin, Cabot Sanmar Ltd. India (1999).
J. Fan and P. Fedkiw, J. Electrochem. Soc.144, 399 (1997).
S.R. Raghavan, M.W. Riley, P.W. Fedkiw and S.A. Khan, Chem. Mater.10, 244 (1998).
S. Panero, D. Satolli, A.D. Epifano and B. Scrosati, J. Electrochem. Soc.149, A414 (2002).
P.E. Stallworth, J.J. Fontanella, M.C. Wintersgill, C.D. Scheidler, J.J. Inomel, S.G. Greenbaum and A.S. Gozdz, J. Power Sources81–82, 739 (1999).
D. Swierczynski, A. Zalewska and W. Wieczorek, Chem. Mater.13, 1560 (2001).
F. Croce, G.B. Appetecchi, L. Persi and B. Scrosati, Nature394, 456 (1998).
O. Bohnke, G. Frand, M. Rezrazi, C. Rrousselot and C. Truche, Solid State Ionics66, 105 (1993).
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Ahmad, S., Ahmad, S. & Agnihotry, S.A. Composite polymeric electrolytes based on PMMA-LiCF3SO3-SiO2 . Ionics 10, 268–272 (2004). https://doi.org/10.1007/BF02382828
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DOI: https://doi.org/10.1007/BF02382828