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Electrochromic phenomena in transition metal oxide thin films prepared by thermal evaporation

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We present an experimental study on the electrochromic properties of MoO3, WO3 and mixed WO3-MoO3 thin films prepared by thermal evaporation. We have constructed symmetric and quasi-symmetric electrochromic cells incorporating the evaporated oxide films as electrochromic layers. Li+ doped V2O5 films served as ion storage layers. The symmetric cells were found to exhibit significantly improved optical properties compared to the quasi-symmetric ones, with very low luminous transmittance values in the colored state, which makes them suitable for large-area window applications.

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8. References

  1. S.K. Deb, J.A. Chopoorian, Journal of Applied Physics37, 4818 (1966).

    Article  CAS  Google Scholar 

  2. S.K. Deb, Appl. Opt. Suppl.3, 193 (1969).

    Google Scholar 

  3. B. Scrosati, Solar Energy Materials and Solar Cells39, 111 (1995).

    Article  CAS  Google Scholar 

  4. C.G. Granqvist, Handbook of inorganic electrochromic materials (Elsevier, Amsterdam, 1995).

    Google Scholar 

  5. J. Zhang, D.K. Benson, J. Electrochem. Soc.144, 2022 (1997).

    CAS  Google Scholar 

  6. A. Agrawal, J.P. Cronin, R. Zhang, Solar Energy Materials, Solar Cells31, 9 (1993).

    CAS  Google Scholar 

  7. E. Khawaja, S.M.A. Durrani, M.A. Daous, J.Phys.: Condens. Matter9, 9381 (1997).

    Article  CAS  Google Scholar 

  8. B. Faughnan, R.S. Crandal, Appl. Phys. Letters31, 834 (1977).

    Article  CAS  Google Scholar 

  9. G. Macrelli, E. Poli, H. Demiryont, R. Gotzelmann, J. Non Crystalline Solids218, 296 (1997).

    Article  CAS  Google Scholar 

  10. Y.F. Yian and O.S. Heavens, Thin Solid Films217, 138 (1992).

    Google Scholar 

  11. M. Anwar, C.A. Hogarth, Int. J. Electronics67, 567 (1989).

    CAS  Google Scholar 

  12. M.S. Jagadeesh, V. Damodara Das, J. Non Crystalline Solids28, 327 (1978).

    Article  CAS  Google Scholar 

  13. M.R. Tubbs, phys. stat. solidi (a)21, 253 (1974).

    CAS  Google Scholar 

  14. G. Leftheriotis, P. Yianoulis, D. Patrikios, Thin Solid Films306, 92 (1997).

    Article  CAS  Google Scholar 

  15. L. Michailovits, I. Hevesi, L. Phan, Z. Varga, Thin Solid Films102, 71 (1983).

    Article  CAS  Google Scholar 

  16. J. Zhang, D.K. Benson, J. Electrochem. Soc.141, 2795 (1994).

    CAS  Google Scholar 

  17. B. Scrosati, in: Applications of Electroactive Polymers (Chapman and Hall), London, 1994, p.250.

    Google Scholar 

  18. O.F. Schirmer, J.Phys. (Paris), Colloque6, 479 (1980).

    Google Scholar 

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Papaefthimiou, S., Leftheriotis, G. & Yianoulis, P. Electrochromic phenomena in transition metal oxide thin films prepared by thermal evaporation. Ionics 4, 321–329 (1998). https://doi.org/10.1007/BF02375873

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  • DOI: https://doi.org/10.1007/BF02375873

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