Abstract
We have obtained a quasioptimal (with respect to the maximin criterion), background-invariant rule for observation of analytical signals from traces of chemical elements using atomic emission spectrometry data. We introduce a dimensionless analytical parameter, and use its dependence on the concentration of the chemical element in the analyte object for determination of lanthanum in aqueous solutions on an inductively coupled plasma atomic emission spectrometer. We present estimates of the accuracy of the determination.
Similar content being viewed by others
References
M. A. Sharaf, D. L. Illman, and B. R. Kowalski, Chemometrics [Russian translation], Khimiya, Leningrad (1989).
M. Thompson and J. N. Walsh, Handbook of Inductively-Coupled Plasma Spectrometry [Russian translation], Nedra, Moscow (1988).
G. M. Bashin, Radiotekh. Élektr.,35, No. 12, 2553 (1990).
B. R. Levin, Theoretical Principles of Statistical Radio Engineering, Vol. 1 [in Russian], Radio i Svyaz’, Moscow (1989).
V. S. Pugachev, Probability Theory and Mathematical Statistics [in Russian], Nauka, Moscow (1979).
E. L. Lehmann, Testing Statistical Hypotheses [Russian translation], Nauka, Moscow (1979).
Additional information
Translated from Izmeritel’naya Tekhnika, No. 8, pp. 63–65, August, 1996.
Rights and permissions
About this article
Cite this article
Bashin, G.M., Savichev, A.T. Asymptotically maximin observation of traces of chemical elements from analytical signals of inductively coupled plasma atomic emission spectrometry. Meas Tech 39, 879–882 (1996). https://doi.org/10.1007/BF02370206
Issue Date:
DOI: https://doi.org/10.1007/BF02370206