Skip to main content
SpringerLink
Log in

Unperturbed dimensions of linear chain polymers in pure and in mixed solvents

  • Original Contribution
  • Polymer Science
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Summary

The unperturbed dimensions of poly (p-tert-butylphenylmethacrylate) and of poly (p-tert-butylcyclohexyl-methacrylate) have been determined from intrinsic viscosity in pure and mixture of solvents by using the semiempirical equation ofStockmayer andFixman.

This dimensions may vary widely depending upon the specific molecular interaction for the case of pure solvents and on the excess thermodynamic properties for the case of mixture of solvents. The results obtained are in agreement with the behaviour of other polymers already reported in the literature.

Zusammenfassung

Es werden die ungestörten Kettendimensionen zweier Polymere in reinen Lösungsmitteln durch Lösungsmittelmischungen bestimmt.

Diese Abmessungen können sowohl von spezifischen molekularen Wechselwirkungen in reinen Lösungsmitteln wie von den thermodynamischen Exzeßgrößen der untersuchten Lösungsmittelmischungen beträchtlich abhängen. Die Ergebnisse stimmen mit ähnlichen in der Literatur beschriebenen Verhaltensweisen anderer Polymerer überein.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Dondos, A. P. andD. Paiterson, J. Polym. Sci. A27, 209 (1969).

    Google Scholar 

  2. Dondos, A., P. Rempp andH. Benoît, J. Polym. Sci.C309 (1970).

  3. Chinai, Suresh, N. andRichard J. Vallss, J. Polym. Sci.39, 363 (1959).

    Article  CAS  Google Scholar 

  4. Marchai, J. etH. Benoît, J. Polymer Scia23, 223 (1957).

    Google Scholar 

  5. Kurata, M. andW. H. Stockmayer, Advan. Polym. Sci.3, 196 (1963).

    CAS  Google Scholar 

  6. Dondos, A. andH. Benoît, Macromolecules4, 279 (1971).

    Article  Google Scholar 

  7. Gargallo, L., Thése, Université de Liége (1971).

  8. Gargallo, L. and V. Desreux (á publier).

  9. Desreux, V., J. Bischoff, Bull. Soc. Chim. Belg.59, 93 (1950).

    CAS  Google Scholar 

  10. Stockmayer, W. A. andM. Fixman, J. Polym. Sci.C-1, 137 (1963).

    Google Scholar 

  11. Flory, P. J. andT. G. Fox, J. Amer. Chem. Soc.73, 1904 (1951).

    CAS  Google Scholar 

  12. Sarkar, D. K. andS. R. Palit, IUPAC. Toronto Meeting. 1968 PreprintA 2, 4.

  13. Salovey, R., J. Polymer Sci.50, S 7 (1961).

    Google Scholar 

  14. Ivin, K. andH. A. Ende, J. Polymer Sci.54, S17 (1961).

    Google Scholar 

  15. Ivin, K., J. A. Ende, andG. Meyerhoff, Polymer3, 129 (1962).

    Article  CAS  Google Scholar 

  16. Mc Glashan, M. L. andR. P. Rastogi, Trans. Faraday Soc.54, 496 (1958).

    CAS  Google Scholar 

  17. Scatchard, G., S. E. Wood andJ. N. Mochel, J. Phys. Chem.43, 119 (1939)

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Facultad de Ciencias Quimicas Departamento de Físico Química, Universidad de Chile, Chile

    G. Ligia Gargallo

Authors
  1. G. Ligia Gargallo
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gargallo, G.L. Unperturbed dimensions of linear chain polymers in pure and in mixed solvents. Colloid & Polymer Sci 253, 288–291 (1975). https://doi.org/10.1007/BF02352077

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02352077

Keywords

Search

Navigation