Radiation induced chain addition of allylbenzene to 1,4-dioxane

  • S. V. Nesterov
  • S. Kücükyavuz
  • A. M. Önal
Letter to the Editor

Abstract

Radiation induced chain addition of allylbenzene to 1,4-dioxane has been studied by IR-, UV-, mass-, NMR- and ESR-spectrometry. Efficiency of the addition depends on the concentration of monomer and it has an optimum atCmonom<0.125M. Apparently, upper concentration limit of the reaction is caused by absorbed energy transfer on the molecule, of monomer followed by energy deactivation. Radiation-chemical yields of the product are 12 and 31 molec./100 eV for 0.125M and 0.07M solution, respectively. The value ofGprod. is an evidence of chain character of the process.

Keywords

Radiation Physical Chemistry Inorganic Chemistry Energy Transfer Concentration Limit 

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Copyright information

© Akadémiai Kiadó 1999

Authors and Affiliations

  • S. V. Nesterov
    • 1
  • S. Kücükyavuz
    • 2
  • A. M. Önal
    • 2
  1. 1.Karpov Institute of Physical ChemistryMoscowRussia
  2. 2.Middle East Technical UniversityAnkaraTurkey

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