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Journal of Radioanalytical and Nuclear Chemistry

, Volume 239, Issue 1, pp 191–196 | Cite as

Correlation of some recoil features in the water-soluble metalloporphyrin ion associate solid system with structural factors

  • H. Shoji
Isotope Chemistry
  • 42 Downloads

Abstract

The recoid feature of central metal atoms in the bi-component solid system of water-soluble metalloporphyrin ion associates was investigated in bremsstrahlung and thermal neutron irradiation at very low temperatures. Very preferable substitution of stable Zn central metal atoms by the Cu* recoil was observed in the system of [M(TMPyP)][M′(TCPP)] (M,M′=Cu, Zn) in both irradiations, while no such tendency was seen in the system of [M(TMPyP)][M′(TPPS)] (M,M′=Cu, Zn). The predominant factor for the difference of the recoil feature is discussed. (H2TMPyP: tetrakis(4-N-methylpyridyl)-porphine, H2TCPP: tetra(p-carboxyphenyl)porphine, H2TPPS: tetra(p-sulfophenyl)-porphine).

Keywords

Physical Chemistry Inorganic Chemistry Structural Factor Metal Atom Central Metal 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Akadémiai Kiadó 1999

Authors and Affiliations

  • H. Shoji
    • 1
  1. 1.Department of ChemistryUniversity of TsukubaTsukuba, IbarakiJapan

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