Skip to main content
Log in

Rearrangement equations for plutonium

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The percents of all oxidation states produced by Pu disproportionation, including unreacted starting material, can be obtained by new equations that are easy to apply. The equations are useful for quantifying the extent and the stoichiometry of disproportionation, the consequences of complexation, and the effects of temperature changes on the composition of the oxidation-state mixture.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. J. Katz, G. T. Seaborg, L. R. Morss, The Chemistry of the Actinide Elements, 2nd ed., Chapman and Hall, Ltd., New York, 1986, p. 823.

    Google Scholar 

  2. G. L. Silver, J. Inorg. Nucl. Chem., 33 (1971) 577 and 4000.

    Article  CAS  Google Scholar 

  3. G. L. Silver, Inorg. Chim. Acta, 154 (1988) 123.

    Article  CAS  Google Scholar 

  4. S. G. Canagaratna, J. Chem. Educ., 69 (1992) 957.

    CAS  Google Scholar 

  5. G. L. Silver, J. Radioanal. Nucl. Chem., 175 (1993), 281. Eq. (3) should be equal to zero in this reference and in Ref. 1 the volume number should be 154. See also USDOE report MLM-3768 (November 1992) p. 19.

    CAS  Google Scholar 

  6. G. L. Silver, J. Inorg. Nucl. Chem., 36 (1974) 939.

    Article  CAS  Google Scholar 

  7. J. M. Cleveland, J. M. Cleveland, The Chemistry of Plutonium, Gordon and Breach, New York, 1970, p. 20.

    Google Scholar 

  8. H. Capdevila, P. Vitorge, E. Giffaut, Radiochim. Acta, 58/59 (1992) 45.

    Google Scholar 

  9. G. L. Silver, Radiochim. Acta, 77 (1997) 189.

    CAS  Google Scholar 

  10. G. L. Silver, J. Radioanal. Nucl. Chem., 203 (1998) 289. This paper provides two reasons that can help understanding why increasing temperature increases the stability of pentavalent plutonium. Other reasons were given more than 25 years ago: see Ref. 14.

    Google Scholar 

  11. G. L. Silver, Radiochim. Acta, 21 (1974) 54.

    CAS  Google Scholar 

  12. G. L. Silver, J. Radioanal. Nucl. Chem., 182 (1994) 291.

    CAS  Google Scholar 

  13. G. L. Silver, USDOE Report MLM-2570, November 1978, p. 14.

  14. G. L. Silver, J. Inorg. Nucl. Chem., 34 (1972) 1857. In this paper, the term “alpha factor” means “alpha coefficient”. See also USDOE Report MLM-2809, April 1981, p. 44.

    Article  CAS  Google Scholar 

  15. H. Capdivila, P. Vitorge, Reply to the Letter of G. L. Silver Commenting on: “Stability of Pentavalent Plutonium”, Radiochim. Acta, 77 (1997) 245.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Silver, G.L. Rearrangement equations for plutonium. J Radioanal Nucl Chem 240, 231–235 (1999). https://doi.org/10.1007/BF02349159

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02349159

Keywords

Navigation