Skip to main content
Log in

Structure of aqueous solutions of tetraethylammonium chloride investigated by positron annihilation and ultrasonic methods

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The structure of aqueous solutions of tetraethylammonium chloride was investigated using compressibility and density measurements and positron annihilation methods. The experimental results are different from those obtained earlier for systems where hydrophobic hydration dominates, although some evidences for formation of cage-like hydrates in liquid phase were observed. The results are interpreted, among others, in terms of competition among different hydrates of the tetraethylammonium cations, hydration of chloride anions, and formation of ionic pairs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. K. Jerie, A. Baranowski, B. Rozenfeld, J. Gliński, S. Ernst, Phys. Scripta, 35 (1987) 729 and references therein.

    CAS  Google Scholar 

  2. Gy. Jákli, A. Baranowski, K. Jerie, J. Gliński, K. Orzechowski, Bull. Pol. Acad. Sci.: Chem., 42 (1994) 71.

    Google Scholar 

  3. See for example:A. H. Narten, S. Lindenbaum, J. Chem. Phys., 51 (1969) 1108 (the system water + Bu4NF); for the collection of possible stoichiometries of clathrate hydrates seeYu. A. Dyadin, Supramolec. Chem., 6 (1995) 59.

    Article  CAS  Google Scholar 

  4. S. Sh. Byk, Yu. F. Makogon, V. I. Fomina, in: Gazovye Gidraty, Izd. Khimia, Moscow, 1980, p. 12.

    Google Scholar 

  5. W.-Y. Wen, J. Solution Chem., 2/3 (1973) 253.

    Google Scholar 

  6. J.-Y. Huot, C. Jolicoeur, in: The Chemical Physics of Solvation, Part A, Theory of Solvation,R. R. Dogonadze, E. Kalman, A. A. Kornyshev, J. Ulstrup (Eds), Elsevier, New York, 1985, p. 417.

    Google Scholar 

  7. H. S. Frank, M. W. Evans, J. Chem. Phys., 13 (1945) 478.

    CAS  Google Scholar 

  8. H. S. Frank, W. Y. Wen, Discuss. Faraday Soc., 24 (1957) 133.

    Article  Google Scholar 

  9. D. W. Davidson, in: Water: A Comprehensive Treatise, Vol. 2, Chap. 3,F. Franks (Ed.), Plenum Press, 1973, p. 115.

  10. K. Jerie, A. Baranowski, B. Rozenfeld, S. Ernst, J. Gliński, Acta Phys. Polon., A64 (1983) 77.

    Google Scholar 

  11. S. Ernst, J. Gliński, B. Jeżowska-Trzebiatowska, Acta Phys. Polon., A64 (1979) 501.

    Google Scholar 

  12. B. E. Convay, R. E. Verrall, J. Phys. Chem., 70 (1966) 3952.

    Google Scholar 

  13. K. Jerie, A. Baranowski, S. Ernst, J. Gliński, Acta Phys. Polon., A69 (1986) 81.

    Google Scholar 

  14. H. Endo, Bull. Chem. Soc. Japan, 16 (1973) 1586.

    Google Scholar 

  15. M. Von Stackelberg, H. Müller, Z. Elektrochem., 58 (1954) 25.

    Google Scholar 

  16. Gy. Jákli, K. Jerie, A. Baranowski, J. Gliński, Acta Phys. Polon., A93 (1998) 649.

    Google Scholar 

  17. G. Kabisch, Ber. Bunsenges. Phys. Chem., 80 (1976) 602.

    CAS  Google Scholar 

  18. The non-compressibility of electrostricted solvation shell of ions is a main assumption of Pasynski's method of determination of solvation numbers from sound velocity data:A. C. Pasynski, Zh. Fiz. Khim., 11 (1938) 608; Zh. Fiz. Khim., 20 (1946) 98.

    Google Scholar 

  19. M.-M. Marciacq-Rousselot, A. De Trobriand, M. Lucas, J. Phys. Chem., 76 (1972) 1455.

    Article  CAS  Google Scholar 

  20. J. Stangret, E. Kamieńska-Piotrowicz, J. Chem. Soc., Faraday Trans., 93 (1997) 3463.

    Article  CAS  Google Scholar 

  21. J. Z. Turner, A. K. Soper, J. L. Finney, J. Chem. Phys., 102 (1995) 5438.

    Article  CAS  Google Scholar 

  22. Gy. Jákli, L. Marko, ACH-Models in Chemistry, 132 (1995) 225.

    Google Scholar 

  23. Gy. Jákli, L. Marko, Thermochim. Acta, 259 (1995) 23.

    Google Scholar 

  24. Gy. Jákli, A. Baranowski, K. Jerie, J. Gliński, K. Orzechowski, Nukleonika, 42 (1997) 123.

    Google Scholar 

  25. U. Kaatze, C. H. Limberg, R. Pottel, Ber. Bunsenges Phys. Chem., 78 (1976) 555.

    Google Scholar 

  26. M. J. Blandamer, M. J. Foster, N. J. Hidden, M. C. R. Symons, Trans. Faraday Soc., 64 (1968) 3247.

    CAS  Google Scholar 

  27. W.-Y. Wen, S. Saito, J. Phys. Chem., 68 (1964) 2639.

    CAS  Google Scholar 

  28. L. C. Aladko, Yu. A. Dyadin, Zh. Obsch. Khim., 66 (1996) 701.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jerie, K., Baranowski, A., Jákli, G. et al. Structure of aqueous solutions of tetraethylammonium chloride investigated by positron annihilation and ultrasonic methods. J Radioanal Nucl Chem 240, 223–229 (1999). https://doi.org/10.1007/BF02349158

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02349158

Keywords

Navigation