Abstract
The complex formation of LaCl3 with dipivaloylmethane (dpm) was investigated in a view of the applicability to a rapid chemistry. It was found that the complex formation of lanthanum chloride with dpm in a gas phase was recognized and a volatile LaCl2 (dpm) which was formed by substitution of a chloride atom in LaCl3 by dpm molecule was mainly produced. A temperature dependence of LaCl2 (dpm) formation was examined and the activation energy of the reaction was deduced.
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Kaneko, T., Tamura, K., Kimura, S. et al. Reaction of LaCl3 with dipivaloylmethane in gas phase. J Radioanal Nucl Chem 240, 53–57 (1999). https://doi.org/10.1007/BF02349136
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DOI: https://doi.org/10.1007/BF02349136