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Analysis of phosphate-related components in Hanford tank wastes

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Abstract

Several organophosphorus compounds including tributyl phosphate (TBP), bis-2-(ethylhexyl) phosphate (D2EHP), and dibutyl butyl phosphonate (DBBP) were used as extractants at the Hanford site. The mass spectral fragmentation patterns of various organosphosphorus compounds have been interpreted and used to predict the identity of phosphate-related components and their degradation products in tank waste.

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References

  1. M. J. Klem, Inventory of Chemicals Used at Hanford Production Plants and Support Operations (1944–1980), WHC-EP-0172, Westinghouse Hanford Company, Richland Washington, 1988.

    Google Scholar 

  2. H. Babad, B. A. Crawford, R. D. Schreiber, J. A. Campbell, G. M. Mong, S. A. Bryan, Chemical and Chemically-Related Considerations Associated with Sluicing Tank C-106 Waste to Tank AY-102. WHC-SD-WM-TI-756, Revision A, Westinghouse Hanford Company and Pacific Northwest National Laboratory Richland Washington, 1996.

    Google Scholar 

  3. W. W. Schultz, G. G. Richardson, An Integrated Lanthanide-Actinide Solvent Extraction Process. In proceedings: American Institute of Chemical Engineers-Nuclear Division meeting December 1970. Chicago, Illinois, Dec. 1970.

  4. J. A. Campbell, R. W. Stromatt, M. R. Smith, D. W. Koppenaal, R. M. Bean, T. E. Jones, D. M. Strachan, H. Babad, Anal. Chem., 66 (1994) 1208A.

    Google Scholar 

  5. J. A. Campbell, R. M. Bean, G. M. Mong, S. A. Clauss, R. B. Lucke, B. D. Lerner, K. E. Grant, R. Steele, V. Hoopes, J. Rau, Flammable Gas Safety Program, Analytical Methods Development: FY 1993 Progress Report, PNL-9062, Pacific Northwest Laboratory, Richland, Washington, 1994.

    Google Scholar 

  6. K. E. Grant, G. M. Mong, S. A. Clauss, K. L. Wahl, J. A. Campbell, J. Radioanal. Nucl. Chem., 220 (1997) 31.

    Article  CAS  Google Scholar 

  7. L. F. Fieser, M. Fieser, Reagents for Organic Synthesis, Vol. 1, John Wiley and Sons, Inc., New York, 1967, p. 192.

    Google Scholar 

  8. A. Streitwieser, C. H. Heathcock, Introduction to Organic Chemistry, McMillan Publishing Co., New York, 1976, p. 503.

    Google Scholar 

  9. H. Tatzel, K. Eiben, A. V. Schoor, D. Stritzke, FORATOM Conf. Trans., Verlag TUV Rheinland, Köln, Germany, 1990, p. 2154.

    Google Scholar 

  10. A. I. Vogel, Practical Organic Chemistry, 3rd ed. Longman Group Ltd, London, UK, 1977, p. 304.

    Google Scholar 

  11. F. W. McLafferty, F. Turecek, Interpretation of Mass Spectra, 4th ed., University Science Books, Sausalito, California, 1993, Section 4. 1, p. 81.

    Google Scholar 

  12. A. K. Postma, D. B. Bechtold, G. G. Borsheim, J. M. Grigsby, R. L. Guthrie, M. Kummerer, M. G. Plys, D. A. Turner, Safety Analysis of Exothermic Reaction Hazards Associated with the Organic Liquid Layer in Tank 241-C-103, WHC-SD-WM-SARR-001, Rev. 0., Westinghouse Hanford Company, Richland Washington, 1994.

    Google Scholar 

  13. K. H. Pool, R. M. Bean, Waste Tank Organic Safety Project, Analysis of Liquid Samples form Hanford Waste Tank 241-C-103, PNL-9403, Pacific Northwest Laboratory, Richland, Washington, 1994.

    Google Scholar 

  14. J. A. Campbell, K. L. Wahl, S. A. Clauss, K. E. Grant, V. Hoopes, G. M. Mong, J. Rau, R. Steele, Organic Tanks Safety Program: Advanced Organic Analysis, FY 1996 Progress Report, PNL-11309, Pacific Northwest National Laboratory, Richland Washington, 1996.

    Google Scholar 

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Mong, G.M., Campbell, J.A. Analysis of phosphate-related components in Hanford tank wastes. J Radioanal Nucl Chem 241, 297–306 (1999). https://doi.org/10.1007/BF02347465

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