Journal of Radioanalytical and Nuclear Chemistry

, Volume 241, Issue 2, pp 265–270 | Cite as

Investigation of the structure of aqueous solutions of 1,2-and 1,4-butanediol by positron annihilation and ultrasonic methods

  • K. Jerie
  • A. Baranowski
  • J. Gliński
  • K. Orzechowski
Article

Abstract

The structure of aqueous solutions of 1,2-butanediol and 1,4-butanediol was investigated using adiabatic compressibility measurements and positron annihilation methods. In the case of 1,2-butanediol the experimental results are very similar to those obtained earlier for systems where hydrophobic hydration dominates. In both cases there are evidences for increased rigidity of the water network, which arises from the formation of hydrogen bonds between diols and water. The usefulness of both the methods applied in investigating the structure of liquid solutions was proved.

Keywords

Hydrogen Physical Chemistry Aqueous Solution Hydration Hydrogen Bond 

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References

  1. 1.
    H. S. Frank, M. W. Evans, J. Chem. Phys., 13 (1945) 478.Google Scholar
  2. 2.
    H. S. Frank, W. Y. Wen, Discuss. Faraday Soc., 24 (1957) 133.CrossRefGoogle Scholar
  3. 3.
    D. W. Davidson, in: Water: A Comprehensive Treatise, Vol. 2,F. Franks (Ed), Plenum Press, 1973, Chap. 3, p. 115.Google Scholar
  4. 4.
    K. Jerie, A. Baranowski, B. Rozenfeld, J. Gliński, S. Ernst, Phys. Scripta, 35 (1987) 729 and papers cited therein.Google Scholar
  5. 5.
    Gy. Jákli, A. Baranowski, K. Jerie, J. Gliński, K. Orzechowski, Bull. Pol. Acad. Sci. Chem., 42 (1994) 71.Google Scholar
  6. 6.
    See for example:S. Ernst, J. Gliński, Mat. Sci., III/3 (1977) 69 (the system water+dioxane).Google Scholar
  7. 7.
    S. SH. Byk, Yu. F. Makogon, V. I. Fomina, in: Gazovye Gidraty, Izd. Khimia, Moscow, 1980, p. 12. For the collection of possible stoichiometries of clathrate hydrates see alsoYu. A. Dyadin, Supramolec. Chem., 6 (1995) 59.Google Scholar
  8. 8.
    A. Baranowski, K. Jerie, J. Gliński, K. Orzechowski, J. Radioanal. Nucl. Chem., 190 (1995) 469.Google Scholar
  9. 9.
    K. Jerie, A. Baranowski, B. Rozenfeld, S. Ernst, J. Gliński, Acta Phys. Polon., A64 (1983) 77.Google Scholar
  10. 10.
    S. Ernst, J. Gliński, B. Jezowska-Trzebiatowska, Acta Phys. Polon., A64 (1979) 501.Google Scholar
  11. 11.
    H. Endo, Bull. Chem. Soc. Japan., 16 (1973) 1586.Google Scholar
  12. 12.
    M. von Stackelberg, H. Müller, Z. Elektrochem., 58 (1954) 25.Google Scholar
  13. 13.
    Gy. Jákli, K. Jerie, A. Baranowski, J. Gliński, Acta Phys. Polon., A93 (1998) 649.Google Scholar
  14. 14.
    K. Jerie, A. Baranowski, S. Ernst, J. Gliński, Acta Phys. Polon., A69 (1986) 81.Google Scholar
  15. 15.
    M. Aratono, T. Toyomasu, M. Villeneuve, Y. Uchizono, T. Takiue, K. Motomura, N. Ikeda, J. Coll. Interface Sci., 191 (1997) 146. See alsoJ. Gliński, G. Chavepeyer, J.-K. Platten, J. Chem. Phys., to be published.Google Scholar
  16. 16.
    J. Gliński, G. Chavepeyer, J.-K. Platten, J. Chem. Phys., 104 (1996) 8816.Google Scholar
  17. 17.
    A. P. Buchikhin, V. J. Goldanski, A. O. Tatur, V. P. Shantarovich, Zh. Eksper. Teor. Fiz., 60 (1971) 1136; Sov. JETP, 33 (1971) 615.Google Scholar
  18. 18.
    S. J. Tao, J. Chem. Phys., 56 (1972) 5499.Google Scholar

Copyright information

© Akadémiai Kiadó 1999

Authors and Affiliations

  • K. Jerie
    • 1
  • A. Baranowski
    • 1
  • J. Gliński
    • 2
  • K. Orzechowski
    • 2
  1. 1.Institute of Experimental PhysicsWrocław UniversityPoland
  2. 2.Faculty of ChemistryWrocław UniversityPoland

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