Chromatographia

, Volume 21, Issue 7, pp 397–401 | Cite as

Extrapolation and interpolation of gas chromatographic retention times

  • R. P. Kozloski
Originals

Summary

An empirical method of extrapolating and interpolating gas chromatographic retention times obtained at three equally spaced isothermal temperatures is described. The accuracy of the method was evaluated from retention time data obtained using packed glass columns. A procedure for constructing retention time tables for homologous series and the derivation of an equation for calculating retention times as a function of temperature is also presented.

Key Words

Gas chromatography Retention time extrapolation Retention time interpolation 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. [1]
    A. B. Littlewood, C. G. S. Phillips, D. T. Price, J. Chem. Soc.158, 1480–1489 (1955).Google Scholar
  2. [2]
    A. J. P. Martin, R. L. M. Synge, Biochem. J.35, 1358–1368 (1941).Google Scholar
  3. [3]
    J. J. van Deemter, F. J. Zuiderweg, A. Klinkerburg, Chem. Eng. Sci.5, 271–289 (1956).Google Scholar
  4. [4]
    S. W. Mayer, E. R. Tompkins J. Amer. Chem. Soc.69, 2866–2874 (1947).CrossRefGoogle Scholar
  5. [5]
    A. T. James, A. J. P. Martin, Biochem. J.50, 679–690 (1952).Google Scholar
  6. [6]
    J. E. Funk, G. Houghton, J. Chromatogr.6, 193–208 (1961).Google Scholar
  7. [7]
    J. E. Funk, G. Houghton, J. Chromatogr.6, 281–291 (1961).Google Scholar
  8. [8]
    H. W. Habgood, W. E. Harris, Anal. Chem.32, 450–453 (1960).Google Scholar
  9. [9]
    J. C. Giddings, J. Chromatogr.4, 11–20 (1960).Google Scholar
  10. [10]
    R. Rowan, Jr., Anal. Chem.33, 510–515 (1961).Google Scholar
  11. [11]
    G. Guiochon, Anal. Chem.36, 661–663 (1964).Google Scholar
  12. [12]
    H. W. Habgood, W. E. Harris, Anal. Chem.36, 663–665 (1964).CrossRefGoogle Scholar
  13. [13]
    R. B. Watts, R. G. O. Kekwick, J. Chromatogr.88, 165–167 (1974).CrossRefGoogle Scholar
  14. [14]
    H. P. Burchfield, E. E. Storrs, “Biochemical Application of Gas Chromatography”, Academic Press, New York, 1962; pp. 81–82.Google Scholar
  15. [15]
    G. Zweig, J. Sherma ed., “Handbook of Chromatography”, Vol II, CPC Press, Boca Raton FL, 1972; p. 16.Google Scholar
  16. [16]
    L. S. Eitre, Chromatographia,6, 489–495 (1973).Google Scholar

Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1986

Authors and Affiliations

  • R. P. Kozloski
    • 1
  1. 1.The Connecticut Agricultural Experiment StationNew HavenUSA

Personalised recommendations