Abstract
The results of the investigation of radiation-thermal hydrodesulphurization of brown coal in presence of methane under accelerated electrons with a dose rate P=350 Gy/s in the intervals of temperatureT=200–500 °C, absorbed dose up to 60 kGy are presented. It has been established that at the more favourable conditions (T=400–450 °C,D>60 kGy) about 80% of sulphur is removed from the coal and in the solid product sulphur decreased up to 1.0–1.1%. In these conditions the selectivity of desulphurization processes iss=2.6–3.8 and energy consumption towards removal of sulphur isE=0.5–0.6 kW h/kg. The mechanism of selective activation by irradiation for the desulphurization process is discussed.
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Mustafaev, I., Mahmudov, O. & Gulieva, N. Radiation-thermal hydrodesulphurization of brown coal. J Radioanal Nucl Chem 242, 177–180 (1999). https://doi.org/10.1007/BF02345914
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DOI: https://doi.org/10.1007/BF02345914