Skip to main content
SpringerLink
Log in

Gamma-radiation initiated addition of allylbenzene to the morpholine

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Radiation induced addition of allylbenzene to morpholine in liquid state was investigated by UV-, IR-spectroscopy and GS/mass spectrometry. Conversion of monomer depends on its initial concentration in the solution and this value is maximum for 0.05M solution. Radiation chemical yield of the product,G prod , increases with concentration of allylbenzene and for 0.15M solution it is equal approximately 9.7 molec/100 eV. This value points on chain character of the process. Final product was identified by electron impact mass-spectrometry. The scheme of the EI induced fragmentation of product is proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. J. McDowell, Sep. Sci. Tech., 23 (1988) 1251.

    CAS  Google Scholar 

  2. M. Lemaire, A. Guy, R. Chomel, J. Foos, J. Chem. Soc., Chem. Commun., 17 (1991) 1152.

    Google Scholar 

  3. E. P. Horwitz, M. L. Dietz, D. E. Fisher, Solv. Extract. Ion Exch., 8 (1990) 557.

    CAS  Google Scholar 

  4. J. F. Dozol, J. Casas, A. M. Sastre, Sep. Sci. Tech., 29 (1994) 1999.

    CAS  Google Scholar 

  5. G. Zirnhelt, M. J. F. Leroy, J. P. Brunette, Y. Frere, Ph. Gramain, Sep. Sci. Tech., 28 (1993) 2419.

    CAS  Google Scholar 

  6. R. M. Izatt, K. Pawlak, J. S. Bradshaw, R. L. Bruening, Chem. Rev., 91 (1991) 1721.

    Article  CAS  Google Scholar 

  7. J. P. Shukla, A. Kumar, R. K. Singh, J. Nucl. Sci. Tech., 31 (1994) 1066.

    CAS  Google Scholar 

  8. V. M. Abashkin, D. W. Wester, J. A. Campbell, K. E. Grant, Radiat. Phys. Chem., 48 (1996) 463.

    Article  CAS  Google Scholar 

  9. M. Draye, A. Favre-Reguillon, J. Foos, A. Guy, M. Lemaire, Radiochim. Acta, 78 (1997) 105.

    CAS  Google Scholar 

  10. E. P. Horwitz, M. L. Dietz, D. E. Fisher, Anal. Chem., 63 (1991) 522.

    Article  CAS  Google Scholar 

  11. S. V. Nesterov, S. Kücükyavuz, A. M. Önal, J. Radional. Nucl. Chem., (in press).

  12. R. M. Silverstein, C. G. Bassler, T. C. Morrill, Spectrometric Identification of Organic Compounds, 3rd ed., Wiley, New York, 1974.

    Google Scholar 

  13. K. Sousy, A. Usanmaz, A. M. Önal, Polymer, 31 (1990) 1564.

    Article  CAS  Google Scholar 

  14. J. H. Beynon, Mass Spectrometry and Its Applications to Organic Chemistry, Elsevier, Amsterdam, 1960.

    Google Scholar 

  15. Q. N. Porter, J. Baldas, Mass Spectrometry of Heterocyclic Compounds, Wiley, New York, 1971, p. 520.

    Google Scholar 

  16. S. V. Nesterov, J. Radioanal. Nucl. Chem., 230 (1998) 273.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Synthetic Polymeric Materials RAS, ul. Profsoyuznaya 70, 117393, Moscow, Russia

    S. V. Nesterov

  2. Middle East Technical University, 06531, Ankara, Turkey

    S. Kücükyavuz & A. M. Önal

Authors
  1. S. V. Nesterov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Kücükyavuz
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. M. Önal
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nesterov, S.V., Kücükyavuz, S. & Önal, A.M. Gamma-radiation initiated addition of allylbenzene to the morpholine. J Radioanal Nucl Chem 242, 91–96 (1999). https://doi.org/10.1007/BF02345898

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02345898

Keywords

Search

Navigation