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Efficient phase transfer of pertechnetate with bicyclic guanidinium compounds

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Abstract

Extraction of pertechnetate with bicyclic guanidinium compounds has been studied in the KTcO4-buffer-H2O/ligand-trichloromethane system. Extraction data of guanidinium ligands have been compared with trialkylmethylammonium (Aliquat 336), tetraphenylphosphonium and tetraphenylarsonium chloride. The lipophilicity of extractants investigated was determined by RP-HPLC. The efficiency of pertechnetate extraction correlates with the lipophilicity of the guanidinium compounds. 1:1 complex formation in the organic phase was observed. The influence of hydroxide, chloride and bicarbonate on the pertechnetate extraction has been investigated. Pertechnetate is extracted with great preference over OH−, Cl− and HCO3 −, ions.

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Authors and Affiliations

  1. Forschungszentrum Rossendorf e. V., Institut für Bioanorganische und Radiopharmazeutische Chemie, D-01314, Dresden, Germany

    H. Stephan, R. Berger, H. Spies & B. Johannsen

  2. Institut für Organische Chemie und Biochemie, Technische Universität München, D-85747, Garching, Germany

    F. P. Schmidtchen

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  1. H. Stephan
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  2. R. Berger
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  3. H. Spies
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Stephan, H., Berger, R., Spies, H. et al. Efficient phase transfer of pertechnetate with bicyclic guanidinium compounds. J Radioanal Nucl Chem 242, 399–403 (1999). https://doi.org/10.1007/BF02345569

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  • DOI: https://doi.org/10.1007/BF02345569

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