Skip to main content
SpringerLink
Log in

Dependence of the methylene selectivity on the composition of hydro-organic eluents for reversed-phase liquid chromatographic systems with alkyl bonded phases

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

A theoretical treatment is presented which considers differences between the composition of the mobile phase and solvents that are incorporated into the bonded phase via preferential sorption. Equations are derived and used to analyze retention data for various homologs chromatographed under reversed-phase conditions using alkyl bonded phases and combinations of water-methanol, water-acetonitrile and watertetrahydrofuran as mobile phases. In the case of water-methanol the surface phase and bulk mobile phase compositions are similar. However, significant differences in composition between the two phases are observed when binary combinations of water-acetonitrile and water-tetrahydrofuran are used as the cluents.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. B. L. Karger, J. R. Gant, A. Hartkopf, P. H. Weiner, J. Chromatogr.,128, 65 (1976).

    Article  CAS  Google Scholar 

  2. P. J. Schoenmakers, H. A. H. Billiet, L. deGalan, J. Chromatogr.,218, 261 (1981).

    CAS  Google Scholar 

  3. P. Dufek, E. Smolkova, J. Chromatogr.,257, 247 (1983).

    Article  CAS  Google Scholar 

  4. P. Dufek, J. Chromatogr.,281, 49 (1983).

    Article  CAS  Google Scholar 

  5. P. Dufek, J. Chromatogr.,299, 109 (1984).

    Article  CAS  Google Scholar 

  6. H. Colin, G. Guiochon, Z. Yun, J. C. Diez-Masa, J. Jandera, J. Chromatogr. Sci.,21, 179 (1983).

    CAS  Google Scholar 

  7. T. Hanai, J. Hubert, J. Chromatogr.,290, 197 (1984).

    Article  CAS  Google Scholar 

  8. T. Hanai, J. Hubert, J. Liq. Chromatogr.,8, 2463 (1985).

    CAS  Google Scholar 

  9. S. M. Petrovic, S. Lomic, I. Sefer, J. Chromatogr.,348, 49 (1985).

    Article  CAS  Google Scholar 

  10. P. C. Sadek, P. W. Carr, M. J. Ruggio, Anal. Chem.,59, 1032 (1987).

    Article  CAS  Google Scholar 

  11. M. E. Gangoda, R. K. Gilpin, J. Chromatogr.,448, 365 (1988).

    Article  CAS  Google Scholar 

  12. I. Z. Atamna, G. M. Muschik, H. J. Issaq, J. Liq. Chromatogr.,12, 2227 (1989).

    CAS  Google Scholar 

  13. H. J. Issaq, M. Jaroniec J. Liq. Chromatogr.,12, 2067 (1989).

    CAS  Google Scholar 

  14. W. J. Cheong, P. W. Carr, J. Chromatogr.,499, 373 (1990).

    Article  Google Scholar 

  15. R. K. Gilpin, M. Jaroniec, S. Lin, Anal. Chem., submitted.

  16. M. Schantz, B. N. Barman, D. E. Martire, J. Res. Nat. Bureau Standards,93, 161 (1988).

    CAS  Google Scholar 

  17. B. P. Johnson, M. G. Khaledi, J. G. Dorsey, J. Chromatogr.,384, 221 (1987).

    Article  CAS  Google Scholar 

  18. J. G. Dorsey, B. P. Johnson, J. Liq. Chromatogr.,10, 2695 (1987).

    CAS  Google Scholar 

  19. K. B. Sentell, J. G. Dorsey, J. Chromatogr.,461, 193 (1989).

    Article  CAS  Google Scholar 

  20. M. Jaroniec, D. E. Martire, J. Chromatogr.,351, 1 (1986).

    Article  CAS  Google Scholar 

  21. M. Jaroniec, D. E. Martire, J. Chromatogr.,387, 55 (1987).

    Article  CAS  Google Scholar 

  22. M. Jaroniec, D. E. Martire, M. Borowko, Adv. Colloid Interface Sci.,22, 177 (1985) and references cited therein.

    Article  CAS  Google Scholar 

  23. D. E. Martire, M. Jaroniec, J. Liq. Chromatogr.,8, 1363 (1985).

    CAS  Google Scholar 

  24. M. Jaroniec, D. E. Martire, J. Oscik, J. Liq. Chromatogr.,9, 2555 (1986).

    CAS  Google Scholar 

  25. L. R. Snyder, “Principles of Adsorption Chromatography”, M. Dekker, New York, 1968.

    Google Scholar 

  26. M. Jaroniec, J. Oscik, J. High Resol. Chromatogr.,5, 3 (1982).

    Article  CAS  Google Scholar 

  27. M. Jaroniec, R. Madey, “Physical Adsorption on Heterogeneous Solids”, Elsevier, Amsterdam, 1988, Chap. 6.

    Google Scholar 

  28. A. Dabrowski, M. Jaroniec, J. Oscik, Surface and Colloid Sci.,14, 83 (1987).

    CAS  Google Scholar 

  29. R. M. McCormick, B. L. Karger, Anal. Chem.,52, 2249 (1980).

    Article  CAS  Google Scholar 

  30. S. S. Yang, R. K. Gilpin, Talanta,36, 327 (1989).

    Article  CAS  Google Scholar 

Download references

Author information

Author notes

  1. M. Jaroniec

    Present address: Chemistry Faculty, M. Curie-Sklodowska University, 20031, Lublin, Poland

Authors and Affiliations

  1. Department of Chemistry, Kent State University, 44242, Kent, Ohio, USA

    R. K. Gilpin, M. Jaroniec & S. Lin

Authors
  1. R. K. Gilpin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Jaroniec
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Lin
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gilpin, R.K., Jaroniec, M. & Lin, S. Dependence of the methylene selectivity on the composition of hydro-organic eluents for reversed-phase liquid chromatographic systems with alkyl bonded phases. Chromatographia 30, 393–399 (1990). https://doi.org/10.1007/BF02328504

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02328504

Key Words

Search

Navigation