Abstract
Mechanical and optical characterization of Hysol 4290 as a function of time and temperature is presented. The kinetic theory of polymers, the Williams, Landel and Ferry equation and the time-temperature superposition principle, is discussed. Rubber-like elasticity is used as a simple experimental method to ascertain if the time-temperature superposition should be expected to apply. Finally, the glass-transition temperature of Hysol 4290 is established and its importance in correctly assessing experimental data is discussed.
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References
Baer, E., ed., Engineering Design for Plastics, Reinhold (1964).
Brinson, H. F., “Studies in Photoviscoelasticity,” Dissertation, Stanford University (1965).
Bueche F., “The Viscoelastic Properties of Plastics,”Jnl. Chem. Phys.,22 (4), (1954)603.
Daniel, I. M., “Quasi-static Properties of a Photoviscoelastic Material,” Experimental Mechanics,5 (3) (1965).
Daniel, I. M., “Static and Dynamic Stress Analysis in Viscoelastic Materials,” Dissertation, Ill. Inst. Tech. (1964).
Dill, E. H., “On the Theory of Photoviscoelasticity,” Univ. Wash. Dept. Aeronautics and Astronautics, Report 63-1 (January, 1963).
Dill, E. H., “Photoviscoelastic Experiments, 1, The Trend in Engineering,”Univ. Wash.,16 (3),5 (1964).
Ferry, J. D., Viscoelastic Properties of Polymers, Wiley (1961).
Flugge, W., Viscoelasticity, Blaisdell (1967).
Hetényi, M., “The Application of Hardening Resins in Three-Dimensional Photoelastic Studies,”Jnl. Appl. Phys.,10,295 (1939).
Lohr, J. J., andDudek, T. J., “Glass Transition Temperatures of Poly (Methyl Methacrylate) Plasticized with Low Concentrations of Monomer and Diethyl Phthalate,”Jnl. Appl. Poly. Sci.,9,3795 (1965).
Mindlin, R. D., “A Mathematical Theory of Photoviscoelasticity,”Jnl. Appl. Phys.,20,206 (1949).
Nielsen, L. E., Mechanical Properties of Polymers, Reinhold (1962).
Read, W. T., “Stress Analysis for Compressible Viscoelastic Materials,”Jnl. Appl. Phys.,21,671 (1950).
Strella, S., “Differential Thermal Analysis of Polymers,”Jnl. Appl. Poly. Sci.,7,569 (1963).
Theocaris, P. S., “Creep and Relaxation Contraction Ratio of Linear Viscoelastic Materials,”Jnl. Mech. and Phys. of Solids,12,125 (1964).
Theocaris, P. S., “Viscoelastic Properties of Epoxy Resins from Creep and Relaxation Tests at Different Temperatures,”Sonderdruck aus Rheologica Acta,2,92 (1962).
Tobolsky, A. V., Properties and Structure of Polymers, Wiley (1960).
Treloar, L. R. G., The Physics of Rubber Elasticity, Oxford (1949).
Williams, M. L. andArenz, R. J., “The Engineering Analysis of Linear Photoviscoelastic Materials,”Experimental Mechanics,4 (9)249 (September1964).
Williams, M. L., Arenz, R. J., Ferguson, C. S. and Kunio, T., “The Mechanical and Optical Characterization of Hysol 8705 with Application to Photoviscoelastic Analysis,” GALCIT SM 63-31, Calif. Inst. Tech. (October 1963).
Williams, M. L., Landel, R. F., andFerry, J. D., “The Temperature Dependence of Relaxation Mechanics in Amorphous Polymers and Other Glass-forming Liquids,”Jnl. Amer. Chem. Soc.,77,3701 (1955).
Wilson, D., “The Thermogravimetric Analyzer and the Residual Gas Analyzer Method for Polymers,” to be published, NASA Ames (1967).
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Brinson, H.F. Mechanical and optical viscoelastic characterization of Hysol 4290. Experimental Mechanics 8, 561–566 (1968). https://doi.org/10.1007/BF02327519
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DOI: https://doi.org/10.1007/BF02327519