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1,3-Thiazepines

4. Reactions of 2-iminothiazepines with methyl acrylate. Crystal and molecular structure of 2-phenylimino-3-(β-methoxycarbonylethyl)- and 2-benzyliminohexahydro-1,3-thiadiazepines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Addition of 2-aryliminohexahydro-1,3-thiazepines to methyl acrylate occurs with participation of the endocyclic nitrogen atom. Structures of the products have been established by IR and mass spectroscopy and x-ray diffraction. The previously described 2-benzylaminotetrahydro-1,3-thiazepine is in fact 2-benzyliminohexahydro-1,3-thiazepine.

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Authors
  1. R. F. Ambartsumova
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  2. B. Tashkhodzhaev
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  3. M. K. Makhmulov
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Additional information

For Communication 3 see [1].

Institute of Phytochemistry, Academy of Sciences, Republic of Uzbekistan, Tashkent 700170. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, 554–559, April, 1997.

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Ambartsumova, R.F., Tashkhodzhaev, B. & Makhmulov, M.K. 1,3-Thiazepines. Chem Heterocycl Compd 33, 475–480 (1997). https://doi.org/10.1007/BF02321396

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  • DOI: https://doi.org/10.1007/BF02321396

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