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Electrostatic interactions in normal and reversed-phase high-performance thin-layer chromatography. Preliminary experiments

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Summary

The retention behaviour of five polycyclic aromatic hydrocarbons having nearly equal ionization potentials but different molecular polarizability values was investigated using normal and reversed-phase high-performance TLC systems. Homologous series of hydrocarbons and n-alcohols were applied as the mobile phases.

The electrostatic interactions operating in these chromatographic systems were analysed by studying the relationship between the log 1/RF values and the molecular polarizabilities of solutes and solvents.

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References

  1. W. A. Bruggeman, J. Van der Steen, O. Hutzinger, J. Chromatogr.238, 335 (1982).

    Article  CAS  Google Scholar 

  2. K. Dadáková, J. Hartl, K. Waisser, J. Chromatogr.254, 277 (1983).

    Article  Google Scholar 

  3. A. M. Barbaro, M. C. Guerra, G. L. Biagi, M. C. Pietrogrande, P. A. Borea, J. Chromatogr.347, 209 (1985).

    Article  CAS  Google Scholar 

  4. M. Bieganowska, E. Soczewiński, M. Jankowska, Chromatographia18, 99 (1984).

    CAS  Google Scholar 

  5. M. C. Guerra, A. M. Barbaro, G. L. Biagi, M. C. Pietrogrande, P. A. Borea, A. Andreani, G. Cantelli-Forti, J. Chromatogr.320, 281 (1985).

    Article  CAS  Google Scholar 

  6. E. Shimada, G. Matsumura, J. Chromatogr.328, 73 (1985).

    Article  CAS  Google Scholar 

  7. A. Kakoulidou, R. F. Rekker, J. Chromatogr.295, 341 (1984).

    Article  CAS  Google Scholar 

  8. G. J. Bijloo, R. F. Rekker, J. Chromatogr.351, 122 (1986).

    Article  CAS  Google Scholar 

  9. H. Lamparczyk, A. Radecki, Chromatographia18, 615 (1984).

    Article  CAS  Google Scholar 

  10. H. Lamparczyk, Chromatographia20, 283 (1985).

    CAS  Google Scholar 

  11. H. Lamparczyk, R. J. Ochocka, Chromatographia21, 409 (1986).

    CAS  Google Scholar 

  12. E. L. Cavalieri, E. G. Rogan, R. W. Roth, R. K. Saugier, A. Hakam, Chem.-Biol. Interactions47, 87 (1983).

    Article  CAS  Google Scholar 

  13. E. Clar, W. Schmidt, Tetrahedron32, 2563 (1976).

    Article  CAS  Google Scholar 

  14. K. J. Miller, J. A. Savchik, J. Amer. Chem. Soc.101, 7206 (1979).

    CAS  Google Scholar 

  15. “Poradnik Fizyko-Chemiczny” (Physico-Chemical Guide Book), Wydawnictwa Naukowo-Techniczne, Warsaw, 1974 p. 120.

  16. H. Engelhardt, G. Ahr, Chromatographia14, 227 (1981).

    CAS  Google Scholar 

  17. E. Tomlinson, H. Hoppe, J. C. Kraak, Int. J. Pharmaceutics7 225 (1981).

    Article  CAS  Google Scholar 

  18. P. Jandera, J. Chromatogr.314, 13 (1984).

    Article  CAS  Google Scholar 

  19. R. M. Smith, J. Chromatogr.324, 243 (1985).

    Article  CAS  Google Scholar 

  20. H. Kalász, Chromatographia18, 629 (1984).

    Article  Google Scholar 

  21. P. C. Sadek, P. W. Carr, R. M. Doherty, M. J. Kamlet, R. W. Taft, M. H. Abraham, Anal. Chem.57, 2971 (1985).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Faculty of Pharmacy, Medical Academy, K. Marksa 107, PL-80416, Gdańsk, Poland

    H. Lamparczyk & R. J. Ochocka

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  1. H. Lamparczyk
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  2. R. J. Ochocka
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Lamparczyk, H., Ochocka, R.J. Electrostatic interactions in normal and reversed-phase high-performance thin-layer chromatography. Preliminary experiments. Chromatographia 23, 337–340 (1987). https://doi.org/10.1007/BF02316179

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  • DOI: https://doi.org/10.1007/BF02316179

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