Summary
The relationship between R M and the concentration of the polar solvent in the moving phase was investigated for a number of aromatic nitro compounds with additional polar groups (amino, methoxy, carbomethoxy, aldehyde). TLC data were correlated with analogous column chromatography results. Linear R M (logk') vs. logX S relationships obtained for both techniques are interpreted in terms of a molecular model of adsorption.
Similar content being viewed by others
References
T. Wawrzynowicz, Chem. Anal. (Warsaw)22, 17 (1977).
E. Soczewiński, Anal. Chem.41, 179 (1969).
E. Soczewiński, W. Gołkiewicz, Chromatographia4, 501 (1971).
W. Gołkiewicz, Chromatographia9, 113 (1976).
E. Soczewiński, J. Chromatogr.130, 23 (1977).
H. Schlitt, F. Geiss, J. Chromatogr.67, 261 (1972).
F. Geiss, Die Parameter der Dünnschicht-Chromatographie, Vieweg, Braunschweig, 1972.
G. R. Duncan, J. Chromatogr.8, 37 (1962).
W. Gołkiewicz, T. Wawrzynowicz, Chromatographia3, 356 (1970).
A. Stołyhwo, O. S. Privett, J. Chromatogr. Sci.11, 20 (1970).
G. Ghersini, E. Cerrai, in “Extraction Chromatography” (eds.T. Braun andG. Ghersini) Elsevier, Amsterdam, 1975, p. 366.
B. Coq, J. P. Nicolas, A. Lamotte, M. Porthault, J. Chromatogr.97, 137 (1974).
E. Soczewiński, W. Gołkiewicz, J. Chromatogr.118, 91 (1976).
E. Soczewiński, T. Dzido, W. Gołkiewicz, K. Gazda, J. Chromatogr.131, 408 (1977).
E. Soczewiński, T. Dzido, W. Gołkiewicz, Chromatographia10, 221 (1977).
L. R. Snyder, Principles of Adsorption Chromatography, Marcel Dekker, New York, 1968.
E. Soczewiński, W. Gołkiewicz, W. Markowski, Chromatographia8, 13 (1975).
L. R. Snyder, J. Chromatogr.8, 319 (1962).
K. F. Reid, Properties and Reaction of Bonds in Organic Molecules, Chapters V, VI, XIV, Longmans, Green and Co., London, 1968.
C. K. Ingold, Structure and Mechanism in Organic Chemistry, 2nd ed., Chapter III, Cornell University Press, Ithaca and London, 1969.
L. R. Snyder, J. Chromatogr.17, 73 (1964).
L. S. Bark, R. J. T. Graham, in “Int. Symp. IV, Chromatog. Electrophorese”, P.A.E., Bruxelles, 1968, pp. 119–127.
L. S. Bark, R. J. T. Graham, Talanta11, 839 (1964).
U. Dabrowska, T. Urbański, Spectrochim. Acta21, 1765 (1965).
P. Jandera, J. Churaček, J. Chromatogr.93, 17 (1974).
P. Jandera, M. Janderova, J. Churaček, J. Chromatogr.115, 9 (1975).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Wawrzynowicz, T., Dzido, T. Solvent composition effects in column and thin layer chromatography of aromatic nitro compounds on alumina. Chromatographia 11, 335–340 (1978). https://doi.org/10.1007/BF02314772
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02314772