, Volume 8, Issue 10, pp 553–558 | Cite as

Separation of secondary alcohols by capillary gas chromatography

  • J. Krupčik
  • K. Tesařik
  • J. Hrivňák


The retention characteristics of C9−C14 secondary alcohols and their acetyl esters were studied on capillary columns coated with Carbowax 1500 and 20M and OV-101 stationary phases. Better separation can be achieved if the secondary alcohols are transformed to their acetyl derivatives. In this form, all isomers of the C9−C14 secondary alcohols could be separated in high efficiency capillary columns caoted with OV-101 and Carbowax 1500. Retention index data for the secondary alcohols and their acetates are also given.


Alcohol Acetate Ester Chromatography Analytical Chemistry 
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  1. [1]
    Krishnan, S., J. Chromatogr.13, 22 (1964).CrossRefGoogle Scholar
  2. [2]
    Evans, M. B. andSmith, J. F., J. Chromatogr.5, 300 (1961).CrossRefGoogle Scholar
  3. [3]
    Šingliar, M., J. Chromatogr.65, 311 (1972).Google Scholar
  4. [4]
    Fábry, T., Thesis, Slovak Technical College, Faculty of Chemical Technology Bratislava, 1972.Google Scholar
  5. [5]
    Schomburg, G. in “Advances in Chromatography”,J. C. Giddings andR. A. Keller, Eds., Vol. 6, M. Dekker, Inc., New York, N. Y., 1968; p. 211.Google Scholar
  6. [6]
    Krupčik, J. andFábry, T., Petrochémia, in press.Google Scholar
  7. [7]
    Krupčik, J., Fábry, T., Galajda, J., Király, J. andŠingliar, M. J. Petrochémia, in press.Google Scholar
  8. [8]
    Littlewood, A. B., “Gas Chromatography”, Second edition, Academic Press, New York, N. Y. 1970; p. 466.Google Scholar
  9. [9]
    Holotík, Š., Leško, J. andKrupčík, J., J. Chromatogr., in pressGoogle Scholar
  10. [10]
    Tesařík, K. andNovotný, M., in “Gas Chromatographie”,H. G. Struppe, Ed., Akademie Verlag, Berlin, 1968; p. 575.Google Scholar
  11. [11]
    Ettre, L. S., “Open Tubular Columns in Gas Chromatography”. Plenum Press, New York, N. Y., 1965.Google Scholar
  12. [12]
    Cram, J. D. andHammond, G. S., “Organic Chemistry”, (in Slovak), Academia Praha, 1969.Google Scholar
  13. [13]
    Leško, J., Holotík, Š., Krupčík, J., andVeselý, V., J. Chromatogr in press.Google Scholar
  14. [14]
    Hrivňák, J., unpublished data.Google Scholar

Copyright information

© Friedr. Vieweg & Sohn, Verlagschesellschaft mbH 1975

Authors and Affiliations

  • J. Krupčik
    • 1
  • K. Tesařik
    • 2
  • J. Hrivňák
    • 3
  1. 1.Department of Analytical Chemistry, Faculty of Chemical TechnologySlovak Technical CollegeBratislavaCzechoslovakia
  2. 2.Institute of Analytical ChemistryCzechoslovak Academy of SciencesBrnoCzechoslovakia
  3. 3.Chemical InstituteKomenský UniversityBratislavaCzechoslovakia

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