Skip to main content
SpringerLink
Log in

Purification of CIS-trimedlure isomers by high-performance liquid chromatography

  • Orginals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

High-performance liquid chromatographic procedures were developed to make it possible to obtain the fourcis-trimedlure isomers (V, W, X, and Y) in pure form. Trimedlure-V and-Y were each readilt separated from the four-componentcis-trimedlure mixture through high-performance liquid chromatographic analysis on 5-μm and 3-μm silica, but trimedlure-W and-X were not adequately resolved. Chromatography of 5-μm silica of the mixtures obtained by epimerization of thetrans-trimedlure isomers, C and B2, yielded the respective epimers, trimedlure-W and-X, in pure form.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. S. Hagen, W. W. Allen, R. L. Tassan, Calif. Agr.35, 5 (1981).

    Google Scholar 

  2. D. S. Jackson, B. G. Lee, Bull. of the ESA31, 29 (1985).

    Google Scholar 

  3. M. Beroza, N. Green, S. I. Gertier, L. F. Steiner, D. M. Miyashita, J. Agric. Food Chem.9, 361 (1961).

    Article  CAS  Google Scholar 

  4. M. Beroza, R. Sarmiento, J. Assoc. Off. Agr. Chem.47, 838 (1964).

    CAS  Google Scholar 

  5. B. A. Leonhardt, T. P. McGovern, J. R. Plimmer, J. High Resol. Chromatogr./Chromatogr. Comm.5, 430 (1982).

    CAS  Google Scholar 

  6. J. D. Warthen, Jr., T. P. McGovern, J. Chromatogr. Sci., in press.

  7. T. P. McGovern, M. Beroza, J. Org. Chem.31, 1472 (1966).

    CAS  Google Scholar 

  8. T. P. McGovern, M. Beroza, K. Ohinata, D. Miyashita, L. F. Steiner, J. Econ. Entomol.59, 1450 (1966).

    CAS  Google Scholar 

  9. P. E. Sonnet, T. P. McGovern, R. T. Cunningham, J. Org. Chem.49, 4639 (1984).

    Article  CAS  Google Scholar 

  10. T. P. McGovern, R. T. Cunningham, B. A. Leonhardt, J. Econ. Entomol.79, 98 (1986).

    CAS  Google Scholar 

  11. R. T. Cunningham, B. A. Leonhardt, T. P. McGovern, R. E. Rice, manuscript in preparation.

Download references

Author information

Authors and Affiliations

  1. Insect Chemical Ecology Laboratory, Agricultural Environmental Quality Institute, Agricultural Research Science, U.S. Department of Agriculture, 20705, Beltsville, Maryland, USA

    J. D. Warthen Jr. & T. P. McGovern

Authors
  1. J. D. Warthen Jr.
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. P. McGovern
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Warthen, J.D., McGovern, T.P. Purification of CIS-trimedlure isomers by high-performance liquid chromatography. Chromatographia 21, 651–654 (1986). https://doi.org/10.1007/BF02311922

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02311922

Key Words

Search

Navigation