, Volume 21, Issue 4, pp 214–218 | Cite as

Studies of adsorption and solution of acetylacetonates of Cr(III), Co(III) and Al(III) by gas chromatography

  • J. Masłowska
  • S. Starzyński


Specific retention volumes, adsorption isotherms, molar heats of solution and changes of the entropy were determined from chromatographic data, which was obtained by the gas chromatographic separation of metal acetylacetonates. The retention data for Cr(III), Co(III) and Al(III) acetylacetonates were measured at different temperatures and different flow rates. From the retention data other values associated with adsorption and solution phenomena were calculated.

Key Words

Gas chromatography Behaviour of metal acetylacetonates Adsorption isotherms Heat of solution 


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  1. [1]
    R. W. Mosbier, R. E. Sievers, Gas Chromatography of Metal Chelates, Pergamon Press, Oxford, 1965.Google Scholar
  2. [2]
    P. C. Uden, D. E. Henderson, Analyst102, 889 (1977).CrossRefGoogle Scholar
  3. [3]
    V. P. Mikhaylenko, I. P. Sereda, A. N. Korol, Zh. Anal. Khim.34, 2260 (1979).Google Scholar
  4. [4]
    J. Masłowska, S. Starzyński, Wiad. Chem.36, 669 (1982).Google Scholar
  5. [5]
    V. P. Mikhaylenko, I. P. Sereda, A. N. Korol, Zh. Anal. Chem.34, 862 (1979).Google Scholar
  6. [6]
    R. Fontaine, C. Pommier, C. Eon, G. Guiochon, J. Chromatogr.104, 1 (1975).CrossRefGoogle Scholar
  7. [7]
    V. P. Mikhaylenko, I. P. Sereda, A. N. Korol, J. Chromatogr.168, 333 (1979).CrossRefGoogle Scholar
  8. [8]
    V. P. Mikhaylenko, I. P. Sereda, A. N. Korol, J. Chromatogr.191, 231 (1980).Google Scholar
  9. [9]
    J. Masłowska, S. Starzyński, Chromatographia17, 418 (1983).Google Scholar
  10. [10]
    J. Masłowska, S. Starzyński, Mikrochim. Acta1984 I, 487.Google Scholar
  11. [11]
    R. G. Charles, J. Pawlikowski, J. Phys. Chem.62, 440 (1958).Google Scholar
  12. [12]
    T. Paryjczak, Chromatografia Gazowa w Badaniach Adsorpcji i Katalizy, PWN, Warszawa, 1975, pp. 56–58, 158.Google Scholar
  13. [13]
    A. N. Korol, Uspehi Chimii,41, 321 (1972).Google Scholar

Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1986

Authors and Affiliations

  • J. Masłowska
    • 1
  • S. Starzyński
    • 1
  1. 1.Institute of General Food ChemistryTechnical University of ŁódźŁódźPoland

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