Summary
The possibility of evaluation of the parameters representing the dispersive solute-solvent interactions is presented. BN and Bs values can be used to describe the liquid phase polarity and to predict the retention indices of alcohols when the model polyxyethylene glycol dialkyl ethers and their sulphur analogs are used as stationary phases. The possibility of the first ionization potentials estimation is also presented.
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Voelkel, A. New stationary phase polarity parameters considering the electric intermolecular interactions in gas chromatographic column. Chromatographia 23, 195–198 (1987). https://doi.org/10.1007/BF02311479
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DOI: https://doi.org/10.1007/BF02311479