Summary
In supercritical fluid chromatography (SFC), studies on binary eluents composed of pentane and diethyleneglycol dimethylether were performed in the concentration rage of 5 to 15% of the ether compound and at pressures of 20 to 50 bar. Influences of temperature, pressure and eluent composition on the behavior of the mobile phase were found to closely resemble those for pentane-dioxane mixtures. Resolution depended on variations in capacity ratios, selectivities, and plate numbers. The critical data for diethyleneglycol dimethylether were estimated by means of different group contribution methods.
Similar content being viewed by others
References
D. Leyendecker, D. Leyendecker, F. P. Schmitz, E. Klesper, J. Chromatogr. in press.
D. Leyendecker, D. Leyendecker, F. P. Schmitz, E. Klesper, J. High Resolut. Chromatogr./Chromatogr. Commun.,9, 566 (1986).
F. P. Schmitz, H. Hilgers, B. Lorenschat, E. Klesper, J. Chromatogr.346, 69 (1985).
F. P. Schmitz, D. Leyendecker, D. Leyendecker, J. Chromatogr. (in press).
D. R. Gere, Science222, 253 (1983).
L. G. Randall, In: “Ultrahigh Resolution Chromatography”, ed.:S. Ahuja, ACS Symp. Ser.250, 135 (1984).
P. Mourier, M. Caude, R. Rosset, Analusis13, 299 (1985).
J. M. Levy, W. M. Ritchey, J. Chromatogr. Sci.,24, 242 (1986).
A. J. Berry, D. E. Games, J. R. Perkins, J. Chromatogr.,363, 147 (1986).
R. C. Reid, J. M. Prausnitz, T. K. Sherwood, “The Properties of Gases and Liquids”, 3rd ed. McGraw-Hill, New York 1977.
K. M. Klincewicz, R. C. Reid, AlChE J.30, 137 (1984).
J. W. Jalowka, T. E. Daubert, Ind. Eng. Chem., Process Des. Dev.25, 139 (1986).
A. P. Kudchadker, G. H. Alani, B. J. Zwolinski, Chem. Rev.68, 659 (1969).
D. Leyendecker, D. Leyendecker, F. P. Schmitz, E. Klesper, J. Chromatogr.,371, 93 (1986).
D. Leyendecker, D. Leyendecker, F. P. Schmitz, B. Lorenschat, E. Klesper, Anal. Chem., submitted.
D. Leyendecker, D. Leyendecker, F. P. Schmitz, E. Klesper, J. High Resolut. Chromatogr./Chromatogr. Commun., submitted.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Leyendecker, D., Schmitz, F.P. & Klesper, E. Influences of temperature, pressure and eluent composition on the behavior of binary eluents at sub- and supercritical conditions. Pentane and diethyleneglycol dimethyl ether. Chromatographia 23, 171–178 (1987). https://doi.org/10.1007/BF02311475
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02311475