Preparation of thermostable, phenyl silicone coated, glass capillary columns for separation of polyaromatic hydrocarbons
- 85 Downloads
A procedure for the preparation of glass capillary columns coated with non-extractable phenyl polysiloxanes has been developed, the phenyl silicone being synthesised in situ in the column. The non-extractability can be explained in terms of a certain degree of crosslinking in the polymer and possibly also by some chemical bonding to the capillary glass wall. Rearrangement of the film at higher temperatures is counteracted by crosslinking in the phase. Column bleeding is thus decreased, and column efficiency is maintained even at higher temperatures. Such capillary columns showed suitable selectivities for separation of polyaromatic hydrocarbons, and the high temperatures necessary for these analyses could be attained.
KeywordsPolymer Silicone Analytical Chemistry Organic Chemistry Hydrocarbon
Unable to display preview. Download preview PDF.
- V. Řehák andE. Smolková, Chromatographia9, 219 (1976).Google Scholar
- K. Grob, Chromatographia10, 625 (1977).Google Scholar
- J. L. Marshall andD. A. Parker, J. Chromatogr.122, 425 (1976).Google Scholar
- D. A. Parker andJ. L. Marshall, in Proceedings of the Second International Symposium on Glass Capillary Chromatography, ed.R. E. Kaiser, Institute of Chromatography, Bad Dürkheim, 1977, p. 299.Google Scholar
- K. Grob Jr. andK. Grob, Chromatographia10, 250 (1977).Google Scholar
- K. D. Barte andM. Novotný, J. Chromatogr.94, 35 (1974).Google Scholar
- C. R. Trash, J. Chromatogr. Sci.11, 196 (1973).Google Scholar
- K. A. Andrianov, Metalorganic Polymers, Interscience, New York, 1965.Google Scholar
- N. F. Ives andL. Giuffrida, J. Ass. Offic. Anal. Chem.53, 973 (1970).Google Scholar