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High-performance liquid chromatographic separation of polyolefin antioxidants and light-stabilisers

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Summary

A scheme was devised for the identification of 22 common antioxidants and light-stabilisers in polyolefins. The separation of these stabilisers was performed by isocratic reversed phase high-performance liquid chromatography on a RP-18 column. Three different separation conditions have been used: the mobile phase composition was 100% acetonitrile (MeCN), 90/10 meCN/H2O and 80/20 MeCN/H2O. The UV254/UV280 ratio and the elution time of each stabiliser were determined for these three mobile phase compositions. The values of UV254/UV280 ratios may be used together with the retention time values for the identification of unknown stabilisers in polyolefin samples.

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Authors and Affiliations

  1. Chemical Research Institute, Centre for Plastics, Timişoara Laboratory and “Solventul” Petrochemical Works, Str. Gării 25, R-1900, Timisoara, Romania

    D. Munteanu, A. Isfan, C. Işfan & I. Tincul

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  1. D. Munteanu
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  2. A. Isfan
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  3. C. Işfan
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  4. I. Tincul
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Munteanu, D., Isfan, A., Işfan, C. et al. High-performance liquid chromatographic separation of polyolefin antioxidants and light-stabilisers. Chromatographia 23, 7–14 (1987). https://doi.org/10.1007/BF02310410

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  • DOI: https://doi.org/10.1007/BF02310410

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