Summary
A reproducible and chemically stable inorganic ion-exchanger, niobium arsenate has been prepared by mixing acidic solutions of niobium sulphate and sodium aresenate in the ratio 1∶4 under different conditions. Its exchange behaviour after heat treatment has been studied. The analytical utility of this material is illustrated by its ability to separate quantitatively Ni(II) from V(V) and Fe(III). Mn(II) from V(V) and Fe(III).
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References
M. Qureshi, J. P. Gupta andV. Sharma, Anal. Chem.45, 1901 (1973).
J. P. Rawat andS. Q. Mujtaba, Canadian J. Chem.53 (17), 2586 (1975).
J. P. Rawat andP. S. Thind, J. Phys. Chem.80, (12), 1384 (1976).
M. Qureshi, J. P. Rawat andA. P. Gupta, J. Chromatog.118, 167 (1976).
G. E. F. Lundell andJ. I. Hoffman, “Outlines of Method of Chemical Analysis 1958”, Wiley, New York, 1958. p. 117.
N. H. Furman, “Standard Methods of Chemical Analysis 1971”, Van Nostrand, New York, 6th Ed. 1971, p. 1026.
E. B. Sandell, “Colorimetric Determination of Traces of Metals 1959”, Interscience, New York, 3rd Ed. 1959, p. 687.
Reference [7], p. 287.
M. Qureshi andS. A. Nabi, J. Inorg. Nucl. Chem.32, 2059 (1970).
M. Qureshi, R. Kumar andH. S. Rathore, Talanta19, 1377 (1972).
M. Qureshi, H. S. Rathore andR. Kumar, J. Chem. Soc. Sec. A 1986 (1970).
J. P. Rawat andJ. P. Singh, Cand. J. Chem.54, 2534 (1976).
G. Albert, U. Constantino, F. Di Gregorio andE. Torracca, J. Inorg. Nucl. Chem.31, 3195 (1969).
A. Clearfield, G. D. Smith andB. Hammond, J. Inorg. Nucl. Chem.30, 277 (1968).
G. Alberti andM. A. Massucci, J. Inorg. Nucl. Chem.32, 1719 (1970).
M. Qureshi, H. S. Rathore andR. Kumar, J. Chromatog.54, 269 (1971).
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Qureshi, M., Rawat, J.P. & Gupta, A.P. Analytical applications of niobium arsenate. Chromatographia 11, 202–205 (1978). https://doi.org/10.1007/BF02302393
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DOI: https://doi.org/10.1007/BF02302393