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Synthesis and properties of dimethylamino-methylporphyrins. A review

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The chemistry of β-and meso-dimethylaminomethylporphyrins is reviewed. These compounds are synthesized by the reduction of intermediate immonium salts or “phosphate complexes” obtained in the Vilsmeier reaction. Special attention was given to the formation of porphyrin carbocations and porphyrin dimers covalently bound through an ethane or ethylene bridge.

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Institute of Biomedical Chemistry, Russian Academy of Medical Sciences, 119832. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1299–1344, October, 1997.

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Ponomarev, G.V. Synthesis and properties of dimethylamino-methylporphyrins. A review. Chem Heterocycl Compd 33, 1127–1166 (1997). https://doi.org/10.1007/BF02290864

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