Summary
The need to determine the migration of toxic unreacted compounds in bisphenol diglycidyl ether epoxy resins prompted us to investigate the HPLC properties of bisphenol F diglycidyl ether and its hydrolysis products in the water-based food simulants 3% (w/v) acetic acid, distilled water and 15% (v/v) ethanol. Peaks were identified by reversed-phase HPLC thermospray mass spectrometry and gas chromatography/mass spectrometry.
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References
L. Henry, K. Neville, “Handbook of Epoxy Resins”, McGraw-Hill, New York, 1982.
J. I. Kroschwitz, “Polymers: An Encyclopedic sourcebook of Engineering Properties”, John Wiley & Sons, New York, 1987.
P. A. Tice, J. D. McGuiness, Food Addit. Contam.4 (3), 267 (1987).
P. A. Tice, Food Addit. Contam.5 (1), 373 (1988).
C. A. May, “Epoxy Resins. Chemistry and Technology”, Marcel Dekker, New York, 1988.
19th Series of the SCF's reports (10th December 1987). Second addendum to the first of the Scientific Committee for Food on certain monomers and other starting substances to be used in the manufacture of plastic materials intended to come into contact with foodstuffs, III/851/86-EN, Rev. 2, 104–125.
W. Heitz, J. Chromatogr.53, 37 (1970).
E. A. Eggers, J. S. Humphrey, Jr., J. Chromatogr.55, 33 (1971).
J. J. Kirkland, P. E. Antle, J. Chromatogr. Sci.15, 137 (1977).
R. V. Vivilecchia, B. G. Lightbody, N. Z. Thimot, H. M. Quinn, J. Chromatogr. Sci.15, 424 (1977).
D. J. Russel, J. Liquid Chromatogr.11 (2), 383 (1988).
W. A. Dark, E. C. Conrad, L. W. Crossman, Jr., J. Chromatogr.91, 247 (1974).
F. P. B. Van der Maeden, M. E. F. Biemond, P. C. G. M. Janssen, J. Chromatogr.149, 539 (1978).
S. A. Meston, C. E. M. Morris, JMS-Rev. Macromol. Chem. Phys. C24 (1), 117 (1984).
D. Noël, K. C. Cole, J. J. Hechler, A. Chouliotis, K. C. Overbury, J. Appl. Polym. Sci.32, 3097 (1986).
D. Noël, K. C. Cole, J. J. Hechler, J. Chromatogr.447, 141 (1988).
A. C. Oomens, F. G. Schuurhuis, Int. Arch. Occup. Environ Health52, 43 (1983).
B. Crathorne, C. P. Palmer, J. A. Stanley, J. Chromatogr.360, 266 (1986).
M.-L. Henriks-Eckerman, T. Laijoki, Analyst113, 239 (1988).
J. Simal Gándara, S. Paz Abuín, P. Paseiro Losada, J. Simal Lozano, J. Chromatogr. Sci., submitted for publication (1992).
P. Paseiro Losada, J. Simal Lozano, S. Paz Abuín, P. López Mahía, J. Simal Gándara, J. Agric. Food Chem., in press (1992).
S. Paz Abuín, M. Pazos Pellín, L. Nuñez Regueira, J. Appl. Polym. Sci.41, 2155 (1990).
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Simal Gándara, J., Paz Abuín, S., López Mahía, P. et al. Identification of RP-HPLC peaks of bisphenol F and of bisphenol F diglycidyl ether and its hydrolysis products by thermospray mass spectrometry and gas chromatography/mass spectrometry. Chromatographia 34, 67–72 (1992). https://doi.org/10.1007/BF02290462
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DOI: https://doi.org/10.1007/BF02290462