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Properties of L-phenylalanine tetraamides as chiral selectors for D,L-amino acids by capillary gas chromatography

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Summary

A wide series of L-phenylalanine tetraamide selectors (Phe-n-O-TA) have been synthesized and used as stationary phases for chiral resolution of D,L-amino acids by capillary gas chromatography. The influence of length and polarity of the oxaalkanoyl bridge spacing the diamide chains of the selectors and the effects of steric hindrance on separating power were investigated. The characteristics of the chiral columns and the separation factors of D,L-n-butyl-N-trifluoroacetyl amino esters are reported.

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References

  1. W. A. König, The Practice of Enantiomer Separation by Capillary Gas Chromatography. Hüthig Verlag, Heidelberg, 1987, p. 1.

    Google Scholar 

  2. V. Schurig, H.-P. Novotny, Angew. Chem. Int. Ed. Engl.29, 939 (1990) and references therein.

    Google Scholar 

  3. G. Palla, A. Dossena, R. Marchelli, J. Chromatogr.349, 9 (1985).

    Google Scholar 

  4. G. Palla, R. Marchelli, A. Dossena, G. Casnati J. Chromatogr.475, 45 (1989).

    Google Scholar 

  5. A. Spisni, R. Corradini, R. Marchelli, A. Dossena, J. Org. Chem.54, 684 (1989).

    Google Scholar 

  6. T. Lodi, R. Marchelli, A. Dossena, E. Dradi, G. Casnati, Tetrahedron38, 2055 (1982).

    Google Scholar 

  7. K. Grob, G. Grob, K. Grob, Jr., Chromatographia10, 181 (1977).

    Google Scholar 

  8. I. Gandolfi, G. Palla, L. Del Prato, F. De Nisco, R. Marchelli, C. Salvadori, J. Food Science57, 377 (1992).

    Google Scholar 

  9. R. Marchelli, A. Dossena, G. Palla, M. Audhuy-Peaudecerf, S. Lefeuvre, P. Carnevali, M. Freddi, J. Sci. Food Agric.59, 217 (1992).

    Google Scholar 

  10. G. Palla, R. Marchelli, A. Dossena, in: Proceedings of the 6. European Conference on Food Chemistry, Hamburg, 1991, p. 269.

  11. I. Gandolfi, G. Palla, R. Marchelli, A. Dossena, S. Puelli, C. Salvadori, J. Food Science, in press.

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Authors and Affiliations

  1. Dipartimento di Chimica Organica e Industriale dell'Università, Viale delle Scienze 1, 43100, Parma, Italy

    R. Corradini, R. Marchelli & G. Palla

Authors
  1. R. Corradini
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  2. R. Marchelli
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  3. G. Palla
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Corradini, R., Marchelli, R. & Palla, G. Properties of L-phenylalanine tetraamides as chiral selectors for D,L-amino acids by capillary gas chromatography. Chromatographia 38, 173–176 (1994). https://doi.org/10.1007/BF02290332

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  • DOI: https://doi.org/10.1007/BF02290332

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