Skip to main content
Log in

Th isotopes in the Santa Monica basin: Temporal variation, long-term mass balance and model rate constants

  • Published:
Journal of Oceanography Aims and scope Submit manuscript

Abstract

Distribution and flux of234Th,232Th and230Th in the water column of central Santa Monica basin observed over a period of seven years show seasonal and interannual variabilities. A steady-state model is applied to the integrated data to calculate long term average flux and model rate constants of Th isotopes. Mass balance calculations show that the basin acts like a closed system for short-lived234Th, but not for the long-lived isotopes230Th and232Th. Most230Th in the basin is transported from elsewhere. Of the incoming Th, 40–55% of the230Th and 14–26% of the232Th enter the surface water in dissolved form. In the upper 100 m, the residence time of dissolved Th with respect to adsorption onto suspended particulates, 70–80 days, is about one order of magnitude higher than the residence time of suspended particles with respect to aggregation into sinking particles, 7–10 days.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Anderson, R. F., M. P. Bacon and P. G. Brewer (1982): Removal of230Th and231Pa at ocean margins.Earth Planet. Sci. Lett.,66, 73–90.

    Google Scholar 

  • Bacon, M. P. and R. F. Anderson (1982): Distribution of thorium isotopes between dissolved and particulate forms in the deep sea.J. Geophys. Res.,87, 2045–2056.

    Google Scholar 

  • Bruland, K. W. and K. H. Coale (1986): Surface water234Th/238U disequilibria: spatial and temporal variations of scavenging rates within the Pacific Ocean. p. 159–172. InDynamic Processes in the Chemistry of the Upper Ocean, ed. by J. D. Burton, P. G. Brewer and R. Chesselet, Plenum, New York.

    Google Scholar 

  • Buat-Menard, H., V. Nguyen, J. L. Reyss, S. Schmidt, Y. Yokoyama, J. La Rosa, S. Heussner and S. W. Fowler (1988): Temporal changes of234Th concentrations and fluxes in the northwestern Mediterranean. p. 121–130. InRadionuclides: A Tool for Oceanography, ed. by J. C. Guary, P. Guegueniat and R. J. Pentreath, Elsevier Science Publishers, London.

    Google Scholar 

  • Chen, J.-H., L. Edwards and G. J. Wasserburg (1986):238U,234U and232Th in seawater.Earth Planet. Sci. Lett.,80, 241–251.

    Google Scholar 

  • Huh, C.-A. and M. P. Bacon (1985): Thorium-232 in the eastern Caribbean Sea.Nature,316, 718–721.

    Google Scholar 

  • Huh, C.-A. and T. M. Beasley (1987): Profiles of dissolved and particulate thorium isotopes in the water column of coastal Southern California.Earth Planet. Sci. Lett.,85, 1–10.

    Google Scholar 

  • Huh, C.-A., W. S. Moore and D. C. Kadko (1989): Oceanic232Th: a reconnaissance and implications of global distribution from manganese nodules.Geochim. Cosmochim. Acta,53, 1357–1366.

    Google Scholar 

  • Huh, C.-A., L. F. Small, S. Niemnil, B. P. Finney, B. M. Hickey, N. B. Kachel, D. S. Gorsline and P. M. Williams (1990): Sedimentation dynamics in the Santa Monica-San Pedro Basin off Los Angeles: radiochemical, sediment trap and transmissometer studies.Continental Shelf Res.,10, 137–164.

    Google Scholar 

  • Huh, C.-A., T.-L. Ku, S. Luo, M. R. Landry and P. M. Williams (1993): Fluxes of Th isotopes in the Santa Monica Basin offshore California.Earth Planet. Sci. Lett.,116, 155–164.

    Google Scholar 

  • Huh, C.-A., J. M. Kelley, J. W. Murray and C.-L. Wei (1994): Water column distribution of230Th and232Th in the Black Sea.Deep-Sea Res.,41, 101–112.

    Google Scholar 

  • Ku, T.-L., K. G. Knauss and G. G. Mathieu (1977): Uranium in open ocean: concentration and isotopic composition.Deep-Sea Res.,24, 1005–1017.

    Google Scholar 

  • Maring, H. B. and R. A. Duce (1987): The impact of atmospheric aerosols on trace metal chemistry.Earth Planet. Sci. Lett.,84, 381–392.

    Google Scholar 

  • Moran, S. B. and K. O. Buesseler (1993): Size-fractionated234Th in continental shelf waters off New England: Implications for the role of colloids in oceanic trace metal scavenging.J. Mar. Res.,51, 893–922.

    Google Scholar 

  • Nozaki, Y., H-S. Yang and M. Yamada (1987): Scavenging of thorium in the ocean.J. Geophys. Res.,92, 772–778.

    Google Scholar 

  • Rea, D. K., M. Leinen and T. R. Janecek (1985): Geological approach to the long-term history of atmospheric circulation.Science,227, 721–725.

    Google Scholar 

  • Taylor, S. R. (1964): Abundance of chemical elements in the continental crust: A new table.Geochim. Cosmochim. Acta,28, 1273–1285.

    Google Scholar 

  • Tsunogai, S., M. Kawasaki and K. Harada (1994): Different partitioning among thorium isotopes in seawater of the northern North Pacific.J. Oceanogr.,50, 197–207.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Huh, CA. Th isotopes in the Santa Monica basin: Temporal variation, long-term mass balance and model rate constants. J Oceanogr 51, 363–373 (1995). https://doi.org/10.1007/BF02285172

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02285172

Keywords

Navigation