Skip to main content
SpringerLink
Log in

Acylation of acetylcellulose with pyromellitic dianhydride

  • Published:
Chemistry of Natural Compounds Aims and scope

Abstract

The cross-linking reactions of acetylcelluloses having different levels of acetyl groups with pyromellitic dianhydride in homogeneous media have been investigated. A relationship has been established between the static exchange capacity (SEC) and the content of hydroxy groups in the acetylcellulose and the exterification conditions (homogeneous or heterogeneous-solid phase). It has been shown that on the interaction of acetylcellulose with pyromellitic dianhydride under homogenous conditions there is a uniform distribution of cross-linkages over the whole length of the acetylcellulose macromolecule, which enables products with high SEC values to be obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. A. Petropavlovskii,Hydrophilic and Partially Substituted Esters and Ethers of Cellulose and their Modification by Chemical Cross-linking [in Russian], Nauka, Leningrad (1988).

    Google Scholar 

  2. G. A. Petropavlovskii and G. R. Rakhmanberdiev,Zh. Prikl. Khim.,39, No. 1, 237 (1966).

    Google Scholar 

  3. G. A. Petropavlovskii, G. R. Rakhmanberdiev, and Kh. U. Usmanov,Cellul. Chem. Technol.,12, No. 2, 153 (1978).

    Google Scholar 

  4. Z. A. Rogovin,The Chemistry of Cellulose [in Russian], Khimiya, Moscow (1972).

    Google Scholar 

  5. G. A. Petropavlovskii, L. K. Yakovenko, and V. G. Vasil'eva,Cellul. Chem. Technol.,10, No. 3, 223 (1976).

    Google Scholar 

  6. L. N. Gonoboblev, G. A. Petropavlovskii, and M. M. Koton,Zh. Prikl. Khim.,52, No. 2, 358 (1979).

    Google Scholar 

  7. Sh. S. Arslanov,Uzb. Khim. Zh., No. 3, 42 (1994).

    Google Scholar 

  8. G. A. Petropavlovskii, N. E. Kotel'nikova, and Sh. S. Arslanov,Khim. Drev., No. 6, 3 (1988).

    Google Scholar 

  9. G. R. Rakhmanberdiev,Water-soluble Acetylcellulose and its Derivatives [in Russian], Author's Abstract of Doctoral Dissertation, Tashkent (1983).

  10. G. A. Petropavlovskii, N. E. Kotel'nikova, and Sh. S. Arslanov,Zh. Prikl. Khim.,62, No. 12, 2803 (1989).

    Google Scholar 

  11. A. V. Obolenskaya, V. P. Shagolev, G. L. Akim, N. L. Kosovich, and I. Z. Emel'yanova,Practical Work on the Chemistry of Wood and Cellulose [in Russian], Lesnaya Prom-st', Moscow (1965).

    Google Scholar 

Download references

Authors
  1. Sh. S. Arslanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Yu. Akmalova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. R. Rakhmanberdyev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Tashkent Institute of Chemical Technology. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 515–520, July–August, 1999.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Arslanov, S.S., Akmalova, G.Y. & Rakhmanberdyev, G.R. Acylation of acetylcellulose with pyromellitic dianhydride. Chem Nat Compd 35, 460–464 (1999). https://doi.org/10.1007/BF02282520

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02282520

Keywords

Search

Navigation