Chromatographia

, Volume 20, Issue 2, pp 102–108 | Cite as

Chromatography of diols. Regularities in the retention of linear diprimary diols in gas-solid and gas-liquid chromatography

  • A. M. Afanassiev
  • V. N. Demeshev
  • E. P. Kalyazin
  • G. V. Kovalev
Originals

Summary

Using various sorbents in gas-liquid chromatography and gas-solid chromatography, the dependence of the retention of diprimary linear diols of the HOCH2(CH2)nCH2−OH type (n=0–4) on different parameters characterizing the physicochemical properties of the diols was studied. As shown, the relationship between the logarithm of the retention volume, or the boiling point, molecular mass, number of CH2-groups, density, refractive index, molecular refraction, and the logarithm of the retention volumes obtained on another stationary phase is either linear or nearly linear. The linear regression coefficients of the various relationships are given.

A change in the free adsorption energy Δ(ΔF) of the diols on Polysorb, Tween and polyethylene glycol 2000 with respect to ethylene glycols was studied. It is shown that Polysorb appeared to be the most specific stationary phase.

Key Words

Gas-liquid chromatography Gas-solid chromatography Retention by Polysorb, PEG and Tween Diols linear diprimary 

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Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1985

Authors and Affiliations

  • A. M. Afanassiev
    • 1
  • V. N. Demeshev
    • 1
  • E. P. Kalyazin
    • 1
  • G. V. Kovalev
    • 1
  1. 1.All-Union Correspondence Institute of Engineering and Lomonosov State UniversityMoscowUSSR

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