Reaction Kinetics and Catalysis Letters

, Volume 5, Issue 2, pp 131–134 | Cite as

Molecular orbital study of the catalytic oxidation of propylene on silver

  • S. Beran
  • P. Jírû
  • B. Wichterlová
  • R. Zahrandík
Article

Abstract

Analysis of the MINDO/2 reaction coordinates concerning the decomposition of the propylene perepoxide radical anion to propylene oxide and propylene peroxide makes it possible to explain the fundamental differences of ethylene and propylene oxidation on silver catalyst.

Keywords

Oxidation Ethylene Physical Chemistry Peroxide Catalysis 

Abstract

Анализ МУПДП/2 реакционных координат разложения анион-радикала перэпоксида пропилена (дающий эпоксид пропилена) дает возможность обБяснить основные различия между окислением этилена и пропилена на серебрянном катализаторе.

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Copyright information

© Akadémiai Kiadó 1976

Authors and Affiliations

  • S. Beran
    • 1
  • P. Jírû
    • 1
  • B. Wichterlová
    • 1
  • R. Zahrandík
    • 1
  1. 1.J. Heyrovský Institute of Physical Chemistry and ElectrochemistryCzechoslovak Academy of SciencesPrague 2Czechoslovakia

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