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Correlation of the retention data of polyaromatic hydrocarbons obtained on various stationary phases used in normal- and reversed-phase liquid chromatography

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Summary

The correlation between the retention data of polyaromatic hydrocarbons (PAH) obtained in normal-and reversed-phase liquid chromatography is investigated in order to determine the dominant factors controlling the retention. It is clear that the separation of PAHs on various chemically-bonded packing materials in normal- and/or reversed-phase modes is primarily controlled by the molecular structure and shape. The π-electron interaction between the solute and the stationary phase also contributes to the retention, although pure silica shows a somewhat different behavior.

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References

  1. “Particulate Polycyclic Organic Matter”, National Academy of Science, Washington, D.C. (1982).

  2. A. Dipple, inC. E. Secule Ed., “Chemical Carcinogens”, ACS Monograph Series 173, American Chemical Society, Washington, D.C. (1976).

    Google Scholar 

  3. D. Schuetzle, F. S. C. Lee, T. J. Prater, S. Tejada, Intern. J. Environ. Anal. Chem.,9, 93 (1981).

    Google Scholar 

  4. G. Löfroth, E. Hefner, I. Alfheim, M. Møller, Science,209, 1037 (1980).

    PubMed  Google Scholar 

  5. M. Popl, V. Dolansky, J. Mostecky, J. Chromatogr.117, 117 (1976).

    Article  Google Scholar 

  6. M. Popl, V. Dolansky, J. Mostecky, J. Chromatogr.,91, 649 (1974).

    Article  Google Scholar 

  7. S. A. Wise, S. N. Clesler, H. S. Hertz, L. R. Hilpert, W. E. May, Anal. Chem.,49, 2306 (1977).

    Article  Google Scholar 

  8. K. G. Liphord, Chromatographia13, 603 (1980).

    Google Scholar 

  9. J. F. Schabron, R. J. Hurtubise, H. F. Silver, Anal. Chem.49, 2253 (1977).

    Article  Google Scholar 

  10. R. J. Hurtubise, T. W. Allen, H. F. Silver, J. Chromatogr.,235, 517 (1982).

    Article  Google Scholar 

  11. R. B. Sleight, J. Chromatogr.,83, 31 (1973).

    Article  Google Scholar 

  12. K. Jinno, K. Kawasaki, Chromatographia,17, 445 (1983).

    Article  Google Scholar 

  13. R. Kaliszan, H. Lamparczyk, J. Chromatogr. Sci.,16, 246 (1978).

    Google Scholar 

  14. N. Tanaka, Y. Tokuda, K. Iwakuchi, M. Araki, J. Chromatogr.,239, 761 (1982).

    Article  Google Scholar 

  15. R. F. Rekker, “The Hydrophobic Fragmental Constants”, Elsevier, Amsterdam, 1977.

    Google Scholar 

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Authors and Affiliations

  1. School of Materials Science, Toyohashi University of Technology, 440, Toyohashi, Japan

    K. Jinno & K. Kawasaki

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  1. K. Jinno
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  2. K. Kawasaki
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Jinno, K., Kawasaki, K. Correlation of the retention data of polyaromatic hydrocarbons obtained on various stationary phases used in normal- and reversed-phase liquid chromatography. Chromatographia 18, 44–46 (1984). https://doi.org/10.1007/BF02279465

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  • DOI: https://doi.org/10.1007/BF02279465

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