Summary
Interaction in the methanol-water system has been studied (i) by the measurement of the mobile phase migration rate in mixed solvents of different composition and (ii) by the changes in chromatographic behaviour of hexacyanoferrate (III) and (II) anions produced by the solvent system. The formation of semi-, mono-, di-, and trihydrates of methanol has been observed. Paper chromatographic separation of hexacyanoferrate (III) and (II) anions has been achieved in the concentration range 85 to 65% (v/v) aqueous methanol, used as a mobile phase.
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Shukla, S.K. Study of the interaction of water with other protic solvents by paper chromatography. Chromatographia 8, 27–32 (1975). https://doi.org/10.1007/BF02279276
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DOI: https://doi.org/10.1007/BF02279276