Summary
The determination of chloride and perchlorate by non-suppressed ion chromatography in aqueous process solutions containing a high sulfate background is described. The method is reliable and fast. The sensitivity for perchlorate is lower than for other anions like nitrate, nitrite and chlorate. The detection limits are about 0.3 μg/ml with linear calibration curves within a concentration range from 1 to 50 μg/ml.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
U. Leffrang, K. Ebert, K. Flory, U. Galla, H. Schmieder, Nuclear Research Center Karlsruhe, results will be published at The Eighth Symposium on Separation Science and Technology for Energy Applications. October 24–28, 1993, Gatlinburg, Tennessee, USA.
A. Dietrich, T. Ledder, D. Gallagher, M. Grabeel, R. Hoehn, Anal. Chem.,64, 496 (1992).
C.Y. Kuo, S. Krasner, G. Stalker, H. Weinberg, S. Howard, Proc. Water Qual. Technol. Conf.; La Verne, CA, USA, 1990; p. 503.
G.O. Franklin, A.W. Fitchett, Pulp Pap. Can.,83, 40 (1982).
O.A. Shpigun, O.N. Obrezkov, Yu.A. Zolotov, Zh. Anal. Khim.,41, 692 (1986).
R.A. Cochrane, D.E. Hillman, J. Chromatogr.,241, 392 (1982).
DIN 38405 Teil 20 Anionen (Gruppe D), September 1991.
N. Dyson, “Chromatographic Integration Methods”, The Royal Society of Chemistry, Cambridge, 1990.
H. Kaiser, Fres. Z. Anal. Chem.,209, 1 (1965).
S. Ebel, “Statistik”, Würzburger Skripten zur Analytik, Reihe, 1, Bayrische Julius-Maximilians Universität Am Hubland, Würzburg, 1992.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Stahl, R. Ion chromatographic determination of chloride, chlorate, and perchlorate in sulfuric acid solutions. Chromatographia 37, 300–302 (1993). https://doi.org/10.1007/BF02278638
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02278638