Summary
A gas chromatographic method using temperature-programmed poly-dimethylsiloxane OV-101 and poly(pheny ether) (5 rings) capillary columns was developed to separate and quantify the reaction by-products in ethylene oligomers. It was found that the content of 2-alkyl-1-alkenes, 2-alkenes and n-alkanes in the C8−C18 α-olefin fractions amounts to 29, 10 and 2.6% respectively.
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Orav, A., Kuningas, K., Koplimets, E. et al. Analysis of reaction by-products in ethylene oligomers by capillary gas chromatography. Chromatographia 37, 259–263 (1993). https://doi.org/10.1007/BF02278630
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DOI: https://doi.org/10.1007/BF02278630