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Separation of low-boiling hydrocarbons by capillary gas chromatography with glass columns treated with hot alkaline solution

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Summary

Soda-lime glass-capillary columns treated with 1M sodium hydroxide at 40–60°C for two days were employed for the gas chromatographic separation of low-boiling hydrocarbons. A 70.5 m×97 μm I.D. column produced 780,000 to 930,000 theoretical plates for early-eluting components. Use of steam-doped carrier gas improved peak shape and column efficiency. The system was successfully applied to the separation of complex mixtures.

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Authors and Affiliations

  1. Department of Applied Chemistry, School of Engineering, Chikusa-ku, 464-01, Nagoya, Japan

    H. Kondo & H. Haraguchi

  2. Research Center for Resource and Energy Conservation, Nagoya University, Chikusa-ku, 464-01, Nagoya, Japan

    T. Takeuchi & H. Haraguchi

Authors
  1. H. Kondo
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  2. T. Takeuchi
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  3. H. Haraguchi
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Kondo, H., Takeuchi, T. & Haraguchi, H. Separation of low-boiling hydrocarbons by capillary gas chromatography with glass columns treated with hot alkaline solution. Chromatographia 33, 169–173 (1992). https://doi.org/10.1007/BF02275900

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  • DOI: https://doi.org/10.1007/BF02275900

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