Summary
The universal retention index has been developed on the basis of a critical analysis of the forms of chromatographic retention data presentation. Methods are presented for the determination of the universal retention index. The advantages of the universal retention index system in the evaluation of the selectivity and classification of stationary phases and in the determination of the composition of binary and polynary stationary phases are discussed. The thermodynamic aspect of the suggested system of chromatographic retention data presentation is also considered.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. S. Vigdergnuz, L. V. Semenchenko, V. A. Ezrets, Yu. N. Bogoslovsky, “Kachestvenny Gazokhromatografichesky Analiz” (Quatitative Gas-Chromatographic Analysis), Nauka Press, Moscow, 1978; p. 15.
Handbuch der Gaschromatographic, edited byE. Leibnitz andH. G. Struppe Akademische Verlagsgesellschaft Geest & Porting K.-G., Leipzig, 1984, p. 15.
E. Kováts, Helv. Chim. Acta41, 1915 (1958).
E. Koválts P. B. Weiss, Ber. Bunsenges. Phys. Chem.69, No. 9-10, 812 (1965).
M.S. Vigdergauz, Abstracts of the 4th All-Union Confer. Thermodynamics of Organic Compounds, Kuibyshev, 1985, p. 171.
N. F. Belyaev, M. S. Vigdergauz, Zh. Analit. Khim.41, 2267 (1986).
N. F. Belyaev, M. S. Vigdergauz, Zh. Analit. Khim.43, 867 (1988).
L. Rohrschneider, J. Chromatogr.22, 6 (1966).
W. O. McReynolds, J. Chromatogr. Sci.8, 685 (1970).
A. B. Littlewood, J. Gas. Chromatogr.1, N11, 16 (1963).
L. Rohrschneider, J. Chromatogr.39, 383 (1969).
M. S. Vigdergauz, “Uspekhi Gazovoy Khromatografii” (Advances in Gas Chromatography), No. 2, All-Union Chem. Society, Kazan, 1970; p. 16.
R. V. Golovya, T. A. Misharina, J. HRC & CC3, 51 (1980).
W. O. McReynolds, Gas Chromatographic Retention Data. Preston Technical Abstracts Co. Niles, Illinois, 1966; p. 333.
G. V. Dmitrieva, N. F. Belyaev, M. S. Vigdergauz, Izv. Akad. Nauk. S.S.S.R., Ser. Khim.6, 1402 (1989).
M. S. Vigdergauz, T. R. Bankovskaya, Chrmatographia9, 548 (1976).
L. V. Semenchenko, M. S. Vigdergauz, J. Chromatogr.245, 177 (1982).
L. V. Semenchenko, Zh. Fizich. Khim.57, 985 (1983).
M. S. Vigdergauz, V. V. Pomazanov, Izv. Akad. Nauk. S.S.S.R., Ser. Khim. N11, 2835 (1971).
N. F. Belyaev, M. S. Vigdergauz, Izv. Vuzov, Khim. i Khimich. Tekhnologiya30, (6), 120 (1987).
N. F. Belyaev, M. S. Vigdergauz, Izv. Vuzov, Khim. i Khimich. Tekhnologiya31, (6), 68, (1988).
E. Kováts, Z. Analyt. Chem.181, 351 (1961).
A. Werhli, E. Kováts, Helv. Chim. Acta,42, 2709 (1959).
N. F. Belyaev, M. S. Vigdergauz, Zh. Analit. Khim.41, 1882 (1986).
M. S. Vigdergauz, Z. Analit. Khim.39, 151 (1984).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Vigdergauz, M.S., Belyaev, N.F. The system of universal retention indices and aspects of its application in gas chromatography. Chromatographia 30, 163–170 (1990). https://doi.org/10.1007/BF02274540
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02274540