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Preparation and gas chromatographic characterization of dibenzyl crown ether stationary phases

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Summary

Two crown ethers, di(tert-butylbenzo)-propyl-15-crown-5 polysiloxane (PSO-DTB-15C5) and dibenzo-propyl-15-crown-5 polysiloxane (PSO-DB-15C5) have been synthesized and coated onto fused-silica capillary columns. The chromatographic characteristics, including column efficiency, polarity, phase transition temperature, operating temperature range and selectivity, were studied.

Excellent selectivity was obtained for the separation of polar position isomers, especially phenol and dinitrotoluene isomers. The separation mechanism is discussed.

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References

  1. C.J. Pedersen, J. Am. Chem. Soc.18, 89, 249 (1967)

    Google Scholar 

  2. I.M. Kolthoff, M.K. Jr. Chantooni, Anal. Chem.,51, 1301 (1979)

    Google Scholar 

  3. R.Sh. Li, J. Chromatogr.,5, 304 (1986)

    Google Scholar 

  4. Y.H. Jin, R.N. Fu, Z.F. Huang, J. Chromatogr.,469, 153 (1989)

    Google Scholar 

  5. E.V. Zagorevskaya, N.Y. Kovalova, J. Chromatogr.,7, 365 (1986)

    Google Scholar 

  6. D.D. Fine, H.L.H. Gearhart, H.A. Mottola, Talant.,32, 751 (1989)

    Google Scholar 

  7. C.A. Rouse, A.C. Finlison, J.B. Tarbet, J.C. Pixton, N.M. Djordjevic, K.E. Markids, J.S. Bradshaw, M.L. Lee, Anal. Chem.,60, 901 (1988)

    Google Scholar 

  8. C.Y. Wu, C.M. Wang, Z.R. Zeng, X.R. Lu, Anal. Chem.,62, 968 (1990)

    Google Scholar 

  9. C.Y. Wu, X.Ch. Zhou, Z.R. Zeng, X.R. Lu, Anal. Chem.,63, 1874 (1991)

    Google Scholar 

  10. C.Y. Wu, J.S. Cheng, Z.R. Zeng, X.R. Lu, S.L. Gong, J. Chromatogr.,594, 243 (1992)

    Google Scholar 

  11. C.Y. Wu, H.Y. Li, Y.Y. Chen, X.R. Lu, J. Chromatogr.,279, 504 (1990)

    Google Scholar 

  12. B.A. Jones, J.S. Bradshaw, M. Ms'hioka, M.L. Lee, J. Org. Chem.,49, 4947 (1984)

    Google Scholar 

  13. J.L. Ge, R.N. Fu, Z.F. Huang, Y.T. Wang, J. Microcolumns Separations,3, 250 (1991)

    Google Scholar 

  14. Z.R. Zeng, C.Y. Wu, Y.H. Fang, Y.T. Wang, J. Chromatogr.,589, 368 (1992).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Wuhan University, 430072, Wuhan, P.R. China

    C. -Y. Wu, L. -S. Cai, Y. -J. Wang, H. -M. Han & Z. -R. Zeng

  2. Hubei Research Institute of Chemistry, 430072, Wuhan, P.R. China

    Z. -Y. Yu & H. Yuan

Authors
  1. C. -Y. Wu
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  2. L. -S. Cai
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  3. Y. -J. Wang
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  4. H. -M. Han
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  5. Z. -R. Zeng
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  6. Z. -Y. Yu
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  7. H. Yuan
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Wu, C.Y., Cai, L.S., Wang, Y.J. et al. Preparation and gas chromatographic characterization of dibenzyl crown ether stationary phases. Chromatographia 37, 374–380 (1993). https://doi.org/10.1007/BF02272251

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  • DOI: https://doi.org/10.1007/BF02272251

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