Skip to main content
SpringerLink
Log in

Separation of oligomeric sugar alcohols by partition chromatography on lon-exchangers

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

Partition chromatography on anion-and cation-exchange resins in aqueous ethanol is used for the separation of aldoheptitols and various oligomeric sugar alcohols. A straight line relationship exists between the logarithm of the distribution coefficient and the degree of polymerization of oligomers with the same mode of glycosidic bonds. At high ethanol concentration the solutes are eluted in order of increasing size whereas at low ethanol concentration the order is reversed. In each oligomeric series there exists a critical concentration at which all oligomers appear simultaneously.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Havlicek, J. andSamuelson, O., Carbohyd. Res.22, 307 (1972).

    Google Scholar 

  2. Lewis, B. A., Smith, F. andStephen, A. M., Methods Carbohyd. Chem.2, 68 (1963).

    Google Scholar 

  3. Peat, S., Whelan, W. J. andLawley, H. G., J. Chem. Soc.724, 1958.

  4. Martinsson, E. andSamuelson, O., J. Chromatog.50, 429 (1970).

    Google Scholar 

  5. Jonsson, P., andSamuelson, O., Science Tools13, 17 (1966).

    Google Scholar 

  6. Arwidi, B. andSamuelson, O., Svensk Papperstid.68, 330 (1965).

    Google Scholar 

  7. Samuelson, O. andStrömberg, H., Carbohyd. Res.3, 89 (1966).

    Google Scholar 

  8. Samuelson, O., Ion Exchange Separations in Analytical Chemistry, Almqvist and Wiksell, Stockholm; Wiley, New York 1963.

    Google Scholar 

  9. Samuelson, O. andStrömberg, H., Acta Chem. Scand.22, 1252 (1968).

    Google Scholar 

  10. Havlicek, J., petersson, G. andSamuelson, O., Acta Chem. Scand.26, 2205 (1972).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Engineering Chemistry, Chalmers University of Technology, Göteborg, Sweden

    J. Havlicek & O. Samuelson

Authors
  1. J. Havlicek
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. Samuelson
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Havlicek, J., Samuelson, O. Separation of oligomeric sugar alcohols by partition chromatography on lon-exchangers. Chromatographia 7, 361–365 (1974). https://doi.org/10.1007/BF02269351

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02269351

Keywords

Search

Navigation