Skip to main content
SpringerLink
Log in

Gas chromatographic study of the urea—Cetyl alcohol adduct and its components

I. Cetyl alcohol and its use as a stationary phase

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

As part of the gas chromatographic study of inclusion compounds, the behaviour of cetyl alcohol (the guest component in the inclusion compound with urea) and its properties as a stationary phase were followed. Measurements were carried out over a temperature range of 40–100°C with a wide selection of substances including aliphatic and aromatic hydrocarbons, halocarbons, alcohols, esters, ethers, carbonyl compounds, amines and organic acids. The experimental retention data were interpreted from the point of view of possible interactions and the contributions from the individual intermolecular forces were evaluated. The results indicated that cetyl alcohol could be used as a stationary phase over a range of 50–90°C for rapid analysis of many non-polar, medium and strongly polar substances.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Mařik, K., Ph. D. Thesis, Faculty of Natural Sciences, Charles University, Prague, 1972.

  2. Knight, H. B., Anal. Chem.24, 1331 (1952).

    Article  Google Scholar 

  3. McAddic, H. G., Can. J. Chem.40, 2195 (1962).

    Google Scholar 

  4. Mařik, K., Smolková, E., Chromatographia6, 420 (1973).

    Google Scholar 

  5. Mařik, K., Smolková, E., J. Chromatogr.91, 303 (1974).

    Article  Google Scholar 

  6. Smolková, E., Lecture in Houston, Texas (U.S.A.), 1974.

  7. Smolková, E., Feltl, L., Všetečka V., J. Chromatogr.148, 3 (1978).

    Article  Google Scholar 

  8. James, A. T., Martin, A. J. P., Biochem. J.52, 238 (1952).

    PubMed  Google Scholar 

  9. Singliar, M., Gas Chromatography in Practice (in Slovak), SUTL, Bratislava, 1961.

    Google Scholar 

  10. Leibnitz, E., Struppe, H. G., Handbuch der Gaschromatographie, Akademie-Verlag, Leipzig 1966, p. 362.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Analytical Chemistry, Charles University, Albertov 2030, 128 40, Prague 2, Czechoslovakia

    E. Smolková, L. Feltl & J. Všetečka

Authors
  1. E. Smolková
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. Feltl
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Všetečka
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Dedicated to the 70th birthday of ProfessorA. A. Zhukhovitskii.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Smolková, E., Feltl, L. & Všetečka, J. Gas chromatographic study of the urea—Cetyl alcohol adduct and its components. Chromatographia 11, 621–626 (1978). https://doi.org/10.1007/BF02268994

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02268994

Keywords

Search

Navigation