Summary
The dependence of the specific surface area of a stationary phase on the phase amount in the packings is of great importance for the detailed study of the solute retention in GLC. Two equations describing this dependence, are derived on the basis of a thermodynamical consideration. The first equation is valid up to the formation of a stationary phase monolayer on the solid surface, while the second after the monolayer formation. The validity of the latter equation has been tested experimentally. A good agreement has been achieved.
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Nikolov, R.N. Dependence of the specific surface area of a stationary phase on the phase amount in the column packings for GLC. Chromatographia 6, 451–455 (1973). https://doi.org/10.1007/BF02268983
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DOI: https://doi.org/10.1007/BF02268983