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Interference of chloride in the speciation of arsenic by ion chromatography

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Summary

The presence of high concentrations of chloride in urine and seawater samples interferes with the separation of arsenic species by ion chromatography; single peaks may be split into two or more discrete peaks, as a result of the large differences in the ionic strengths of the mobile and injection solvents. A simple model is proposed to explain this phenomenon.

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Authors and Affiliations

  1. Division of Energy Chemistry, Lucas Heights Research Laboratories, CSIRO, Private Mail Bag 7, 2232, Sutherland, NSW, Australia

    G. K. -C. Low, G. E. Batley & S. J. Buchanan

Authors
  1. G. K. -C. Low
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  2. G. E. Batley
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  3. S. J. Buchanan
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Low, G.K.C., Batley, G.E. & Buchanan, S.J. Interference of chloride in the speciation of arsenic by ion chromatography. Chromatographia 22, 292–298 (1986). https://doi.org/10.1007/BF02268777

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  • DOI: https://doi.org/10.1007/BF02268777

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