Summary
Poly(methyl-3-propylthiol)siloxane has been evaluated for use as stationary phase in open tubular columns for gas and supercritical fluid chromatography. Immobilization of the stationary phase was achieved by crosslinking with 2,4,6-trichloro-1,3,5-triazine. The poly(methyl-3-propylthiol)siloxane stationary phase film was in situ oxidized to the disulphide and sulphonic acid forms and both have been evaluated for use in supercritical fluid chromatography. Good selectivity towards polar polycyclic aromatic compounds has been shown. All the modified forms of the stationary phase were loaded with silver ions and were evaluated with regard to ligand exchange chromatography using supercritical fluid carbon dioxide as a mobile phase. The utility of the stationary phase, having sulphonic acid groups loaded with silver ions, has been demonstrated by separation of fatty acid methyl esters according to their unsaturation.
Similar content being viewed by others
References
V.A. Davankov, A.V. Semechkin, J. Chromatogr.141, 313 (1977).
O.K. Guha, J. Janák, J. Chromatogr.68, 325 (1972).
V. Schurig, W. Bürkle, K. Hintzer, R. Weber, J. Chromatogr.475, 23 (1989).
E. Lundanes, T. Greibrokk, J. Chromatogr.349, 439 (1985).
R.M. Campbell, N.N. Djordjevic, K.E. Markides, M.L. Lee, Anal. Chem.60, 356 (1988).
M. Demirbüker, L.G. Blomberg, J. Chromatogr. Sci.28, 67 (1990).
M. Demirbüker, L.G. Blomberg, J. Chromatogr.550, 765 (1991).
M. Demirbüker, I. Hägglund, L.G. Blomberg, J. Chromatogr., in press.
V. Schurig, D. Schmalzing, M. Schleimer, Angew. Chem. Int. Ed. Engl.30, 987 (1991).
R. Brügger, P. Krähenbühl, A. Marti, R. Straub, H. Arm, J. Chromatogr.557, 163 (1991).
A. Marti, P. Krähenbühl, R. Brügger, H. Arm, Chimia45, 13 (1991).
P. Petersson, K.E. Markides, D.F. Johnson, B.E. Rossiter, J.S. Bradshaw, M.L. Lee, J. Microcol. Sep.4, 155 (1992).
D. Barton, W.D. Ollis, Comprehensive Organic Chemistry, The Synthesis and Reaction of Organic Compounds, Vol. 3: Sulphur, Selenium, Silicon, Boron, Organometallic Compounds,D.N. Jones, ed., Pergamon Press, Oxford, 1979.
J.A. Dunn, K.B. Holland, J.R. Jezorek, J. Chromatogr.394, 375 (1987).
S.D. Fazio, J.B. Crowther, R.A. Hartwick, Chromatographia18, 216 (1984).
Z. Juvancz, M.M. Schirmer, D.F. Johnson, K.E. Markides, J.S. Bradshaw, M.L. Lee, J. Microcol. Sep.3, 349 (1991).
S.R. Müller, W. Simon, H.M. Widmer, K. Grolimund, G. Schomburg, P. Kolla, Anal. Chem.61, 2747 (1989).
J. Olsson, Diploma work, University of Stockholm, 1992.
D. Barton, W.D. Ollis, Comprehensive Organic Chemistry, The Synthesis and Reactions of Organic Compounds, Vol. 4: Heterocyclic Compounds,P.G. Sammes, ed., Pergamon Press, Oxford, 1979.
A. Bemgård, L. Blomberg, M. Lymann, S. Claude, R. Tabacchi, J. High Resolut. Chromatogr./Chromatogr. Commun.10, 302 (1987).
E.J. Guthrie, H.E. Schwartz, J. Chromatogr. Sci.24, 236 (1986).
W.W. Christie, J. Lipid Res.23, 1072, (1982).
C.N. Yiannios, J.V. Karabinos, J. Org. Chem.28, 3246 (1963).
B. Phillips, P.S. Starcher, B.D. Ash, J. Org. Chem.23, 1823 (1959).
K.D. Bartle, C.L. Woolley, K.E. Markides, M.L. Lee, R.S. Hansen, J. High Resolut. Chromatogr./Chromatogr. Commun.10, 128 (1987).
A. Bemgård, L. Blomberg, M. Lymann, S. Claude, R. Tabacchi, J. High Resolut. Chromatogr./Chromatogr. Commun.11, 881 (1988).
T. Alsberg, U. Stenberg, R. Westerholm, M. Strandell, U. Rannug, A. Sundvall, L. Romert, V. Bernson, B. Pettersson, R. Toftgård, B. Franzén, M. Jansson, J.Å. Gustafsson, K.E. Egebäck, G. Tejle, Environ. Sci. Technol.19, 43 (1985).
K. Janák, J. Janák, Chem. Listy75, 465 (1981).
Author information
Authors and Affiliations
Additional information
Dedicated to Professor Leslie S. Ettre on the occasion of his 70th birthday.
Rights and permissions
About this article
Cite this article
Janák, K., Demirbüker, M., Hägglund, I. et al. Modifications of poly(methyl-3-propylthiol)siloxane to give stationary phases for open tubular supercritical fluid chromatography. Chromatographia 34, 335–341 (1992). https://doi.org/10.1007/BF02268365
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02268365